Coordination geometry in metallo-supramolecular polymer networks

B Hosseinzadeh, M Ahmadi - Coordination Chemistry Reviews, 2022 - Elsevier
Nature employs a wide library of transient interaction to operate adaptively on various time
and length scales. Inspired by such elegant designs, combinations of different …

A comprehensive review on poly (3-alkylthiophene)-based crystalline structures, protocols and electronic applications

S Agbolaghi, S Zenoozi - Organic Electronics, 2017 - Elsevier
Abstract Poly (3-alkylthiophenes)(P3ATs) particularly poly (3-hexylthiophene)(P3HT) have
vigorous tendency to crystallize into the ordered morphologies, thereby reflect the efficient …

End-group chemistry and junction chemistry in polymer science: past, present, and future

J Kim, HY Jung, MJ Park - Macromolecules, 2020 - ACS Publications
The current goal in functional polymeric material research is the preparation of polymers
with high-fidelity nanoscale self-assembled structures and advanced functionality. Thus …

Nickel(II)-catalyzed living polymerization of diazoacetates toward polycarbene homopolymer and polythiophene-block-polycarbene copolymers

L Zhou, L Xu, X Song, SM Kang, N Liu… - Nature Communications, 2022 - nature.com
Diazoacetate polymerization has attracted considerable research attention because it is an
effective approach for fabricating carbon–carbon (C–C) main chain polymers. However …

Multicomponent metallo-supramolecular nanocapsules assembled from calix [4] resorcinarene-based terpyridine ligands

L He, SC Wang, LT Lin, JY Cai, L Li… - Journal of the …, 2020 - ACS Publications
Tetrafunctionalized calix [4] resorcinarene cavitands commonly serve as supramolecular
scaffolds for construction of coordination-driven self-assembled capsules. However, due to …

Combinations (Є) among controlled/living polymerizations and utilizations of efficient chemical reactions for the synthesis of novel polymeric materials

YS Huang, DD Ejeta, SW Kuo, Y Nakamura… - Polymer …, 2023 - pubs.rsc.org
Building on the 1st-generation method of living anionic polymerization in the 1950s, various
2nd-gen controlled/living polymerization (CLP) techniques were developed in the 1980s …

Connectivity defects in metallo-supramolecular polymer networks at different self-sorting regimes

M Ahmadi, L Löser, G Pareras, A Poater… - Chemistry of …, 2023 - ACS Publications
The properties of polymer networks depend on their connectivity, specifically on the
presence of connectivity defects like loops and dangling ends. While chemically crosslinked …

Conformational regulation of multivalent terpyridine ligands for self-assembly of heteroleptic metallo-supramolecules

SC Wang, KY Cheng, JH Fu, YC Cheng… - Journal of the …, 2020 - ACS Publications
A two-ligand system composed of the predesigned multivalent and complementary
terpyridine-based ligands was exploited to construct heteroleptic metallo-supramolecules …

Self-sorting of transient polymer networks by the selective formation of heteroleptic metal–ligand complexes

M Ahmadi, A Poater, S Seiffert - Macromolecules, 2023 - ACS Publications
Advances in self-sorting mechanisms have resulted in the development of a broad library of
well-defined supramolecular coordination complexes (SCCs) with unprecedented …

“Rod–coil” copolymers get self-assembled in solution

F Xu, J Zhang, P Zhang, X Luan, Y Mai - Materials Chemistry Frontiers, 2019 - pubs.rsc.org
Supramolecular self-assembly of amphiphilic “rod–coil” copolymers in solution has attracted
tremendous interest, as they exhibit distinct self-assembly behaviors profiting from the …