Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
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Bis-Ferrocenyl-Pyridinediimine Trinuclear Mixed-Valent Complexes with Metal-Binding Dependent Electronic Coupling: Synthesis, Structures, and Redox …

C Carter, Y Kratish, T Jurca, Y Gao… - Journal of the American …, 2020 - ACS Publications
A family of metal dichloride complexes having a bis-ferrocenyl-substituted pyridinediimine
ligand was systematically synthesized ((Fc2PDI) MCl2, M= Mg, Zn, Fe, and Co) and …

Ferrocenyl-based di-and trinuclear lanthanide complexes: solid state structures,(spectro) electrochemical and DFT studies

A Khalladi, E Kovalski, MA Abdulmalic, T Rüffer… - Dalton …, 2023 - pubs.rsc.org
Dinuclear and trinuclear ferrocenylcarboxylato-bridged lanthanide complexes of type [Ln
(μO: κ2OO′-O2CFc)(O2CFc) 2 (H2O)(dmf)] 2·(dmf) 2 (Ln= Sm (2), Eu (3), Gd (4), Tb (5); Fc …

Transition-Metal Carbonyl Complexes of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

D Miesel, A Hildebrandt, M Korb… - …, 2015 - ACS Publications
Pentacarbonyl (2, 5-diferrocenyl-1-phenyl-1 H-phosphole) metal complexes 3a–c (3a, M=
Cr; 3b, M= Mo; 3c, M= W) have successfully been synthesized by the reaction of 2, 5 …

Ferrocenyl‐Pyrenes, Ferrocenyl‐9, 10‐Phenanthrenediones, and Ferrocenyl‐9, 10‐Dimethoxyphenanthrenes: Charge‐Transfer Studies and SWCNT …

A Preuß, S Notz, E Kovalski, M Korb… - … A European Journal, 2020 - Wiley Online Library
Abstract The synthesis of 1‐Fc‐(3), 1‐Br‐6‐Fc‐(5 a), 2‐Br‐7‐Fc‐(7 a), 1, 6‐Fc2‐(5 b), 2, 7‐
Fc2‐pyrene (7 b), 3, 6‐Fc2‐9, 10‐phenanthrenedione (10), and 3, 6‐Fc2‐9, 10 …

Anion and solvent dependency of the electronic coupling strength in mixed valent class II systems

A Hildebrandt, D Miesel, Q Yuan, J Freytag… - Dalton …, 2019 - pubs.rsc.org
The influence of the coordination and ion pairing properties of electrolyte anions on
electronic coupling in cationic class II mixed valent species was studied. In order to cover a …

Tuning Electron-Transfer Properties in 5, 10, 15, 20-Tetra (1′-hexanoylferrocenyl) porphyrins as Prospective Systems for Quantum Cellular Automata and Platforms …

NR Erickson, CD Holstrom, HM Rhoda… - Inorganic …, 2017 - ACS Publications
Metal-free (1) and zinc (2) 5, 10, 15, 20-tetra (1′-hexanoylferrocenyl) porphyrins were
prepared using an acid-catalyzed tetramerization reaction between pyrrole and 1′-(1 …

Ferrocenyl naphthalenes: substituent-and substitution pattern-depending charge transfer studies

A Preuß, M Korb, D Miesel, T Rüffer… - Dalton …, 2019 - pubs.rsc.org
The synthesis of a series of ferrocenyl-functionalized naphthalenes of type 2-Fc-C10H7 (3a),
1-Fc-2-R-C10H6 (3b, R= OMe; 3c, R= Me; 3d, R= H; 3e, R= CH (O)), 1, 1′-(C10H7) …

Synthesis, characterization, and electrochemistry of diferrocenyl β-diketones,-diketonates, and pyrazoles

SW Lehrich, J Mahrholdt, M Korb, A Hildebrandt… - Molecules, 2020 - mdpi.com
The synthesis of FcC (O) CH (R) C (O) Fc (Fc= Fe (η5-C5H4)(η5-C5H5); R= H, 5; n Bu, 7;
CH2CH2 (OCH2CH2) 2OMe, 9),[M (κ2 O, O′-FcC (O) CHC (O) Fc) n](M= Ti, n= 3, 10; M …