Molecular barrels as potential hosts: from synthesis to applications

R Banerjee, D Chakraborty… - Journal of the American …, 2023 - ACS Publications
Self-assembled discrete molecular architectures that show selective molecular recognition
within their internal cavities are highly desirable. Such hosts often show guest recognition …

Metallacycle/metallacage-cored supramolecular networks

R Zhang, R Li, F Huang, M Zhang - Progress in Polymer Science, 2023 - Elsevier
Supramolecular networks often possess good dynamic features but suffer from low
mechanical properties. Supramolecular coordination complexes including metallacycles …

Bifunctional {Pb10K2}–Organic Framework for High Catalytic Activity in Cycloaddition of CO2 with Epoxides and Knoevenagel Condensation

S Liu, H Chen, X Zhang - ACS Catalysis, 2022 - ACS Publications
Seeking strategies to enhance the chemical stability of metal–organic framework (MOF)
materials has become a focus for practical applications, which prompts us to carry out the …

Fluorine-Functionalized NbO-Type {Cu2}-Organic Framework: Enhanced Catalytic Performance on the Cycloaddition Reaction of CO2 with Epoxides and …

H Chen, T Zhang, S Liu, H Lv, L Fan… - Inorganic Chemistry, 2022 - ACS Publications
The high catalytic activity of metal–organic frameworks (MOFs) can be realized by
increasing their effective active sites, which prompts us to perform the functionalization on …

Water-soluble self-assembled cage with triangular metal–metal-bonded units enabling the sequential selective separation of alkanes and isomeric molecules

LJ Wang, S Bai, YF Han - Journal of the American Chemical …, 2022 - ACS Publications
The selective separation of structurally similar aliphatic/aromatic hydrocarbons is an
essential goal in industrial processes. In this study, we report the synthesis of a water …

Nanocage-Based Tb3+-Organic Framework for Efficiently Catalyzing the Cycloaddition Reaction of CO2 with Epoxides and Knoevenagel Condensation

H Lv, H Chen, L Fan, X Zhang - Inorganic Chemistry, 2022 - ACS Publications
The catalytic performance of metal–organic framework (MOF)-based catalysts can be
enhanced by increasing their catalytic sites, which prompts us to explore the multicore …

Emissive Metallacage‐Cored Polyurethanes with Self‐Healing and Shape Memory Properties

K Gao, Q Feng, Z Zhang, R Zhang, Y Hou… - Angewandte …, 2022 - Wiley Online Library
The structures of the crosslinks in supramolecular polymer networks play an important role
on their properties and functions. Herein, emissive metallacages are used as crosslinks to …

Dynamic Metallosupramolecular Cages Containing 12 Adaptable Pockets for High-Order Guest Binding Beyond Biomimicry

YH Huang, YL Lu, J Ruan, SP Zheng… - Journal of the …, 2023 - ACS Publications
Molecular recognition lies at the heart of biological functions, which inspires lasting research
in artificial host syntheses to mimic biomolecules that can recognize, process, and transport …

Structural Switching of a Distorted Trigonal Metal‐Organic Cage to a Tetragonal Cage and Singlet Oxygen Mediated Oxidations

R Banerjee, D Chakraborty, WT Jhang… - Angewandte Chemie …, 2023 - Wiley Online Library
Construction of metal–organic cages with unique architecture and guest binding abilities is
highly desirable. Herein, we report the synthesis of a distorted trigonal cage (1) from a …

Highly Robust {In2}–Organic Framework for Efficiently Catalyzing CO2 Cycloaddition and Knoevenagel Condensation

S Liu, H Chen, L Fan, X Zhang - Inorganic Chemistry, 2023 - ACS Publications
To improve the catalytic performance of metal–organic frameworks (MOFs), creating higher
defects is now considered as the most effective strategy, which can not only optimize the …