Chiral molecules with multiple stereocenters are widely distributed in nature and drugs.
Asymmeric catalysis has allowed the formation of a chiral molecule's enantiomers with equal …

The recent advances in the N‐heterocyclic carbene (NHC)‐organocatalyzed generation of
azolium enolate intermediates and their subsequent interception with electrophiles are …

The first enantioselective formal [5+ 4] cycloaddition is realized under palladium catalysis to
deliver benzofuran-fused nine-membered rings. These medium-sized heterocycles and …

Abstract The first catalytic formal [5+ 4] cycloaddition to prepare nine‐membered
heterocycles is presented. Under palladium catalysis, the reaction of N‐tosyl azadienes and …

The first highly enantioselective phosphine‐catalyzed formal [4+ 4] annulation has been
developed. In the presence of amino‐acid‐derived phosphines, the unprecedented [4+ 4] …

Abstract The palladium‐catalyzed asymmetric [4+ 3] cyclization of trimethylenemethane
donors with benzofuran‐derived azadienes furnishes chiral benzofuro [3, 2‐b] azepine …

A novel Pd0‐catalyzed asymmetric [4+ 3] annulation reaction of two readily accessible
starting materials has been developed for building seven‐membered heterocyclic …

Asymmetric diastereodivergent catalysis is a powerful strategy for accessing different
stereoisomers of a molecule, which are important in the discovery of biologically and …

We disclose that the carbonates of 4‐hydroxy‐2‐cyclopentenones can form π‐allylpalladium‐
based 1, 2‐carbodipoles, which isomerize to interesting η2‐Pd0‐cyclopentadienone …

A novel Pd0‐catalyzed highly regio‐and enantioselective [3+ 2] spiroannulation reaction
has been developed for rapid assembly of a new class of [5, 5] spirocyclic carbo‐and …