Endohedral fullerenes

AA Popov, S Yang, L Dunsch - Chemical reviews, 2013 - ACS Publications
One of the attractive properties of the hollow carbon clusters, known as fullerenes, is the
possibility to use them as robust containers for other species. Although an IUPAC …

When metal clusters meet carbon cages: endohedral clusterfullerenes

S Yang, T Wei, F Jin - Chemical society reviews, 2017 - pubs.rsc.org
Fullerenes have the characteristic of a hollow interior, and this unique feature triggers
intuitive inspiration to entrap atoms, ions or clusters inside the carbon cage in the form of …

Current status and future developments of endohedral metallofullerenes

X Lu, L Feng, T Akasaka, S Nagase - Chemical Society Reviews, 2012 - pubs.rsc.org
Endohedral metallofullerenes (EMFs), a new class of hybrid molecules formed by
encapsulation of metallic species inside fullerene cages, exhibit unique properties that differ …

[图书][B] Organic electrochemistry

O Hammerich, B Speiser - 2016 - api.taylorfrancis.com
Organic electrochemistry is concerned with the reduction and oxidation of organic molecules
at electrodes. Although it is now more than 200 years ago that the so-called Volta pile was …

Two Metastable Endohedral Metallofullerenes Sc2C2@C1(39656)-C82 and Sc2C2@C1(51383)-C84: Direct-C2-Insertion Products from Their Most …

YR Yao, ZC Chen, L Chen, SY Zheng… - Journal of the …, 2023 - ACS Publications
Endohedral metallofullerenes (EMFs) are sub-nano carbon materials with diverse
applications, yet their formation mechanism, particularly for metastable isomers, remains …

Endohedral metallofullerene molecular nanomagnets

Z Hu, S Yang - Chemical Society Reviews, 2024 - pubs.rsc.org
Magnetic lanthanide (Ln) metal complexes exhibiting magnetic bistability can behave as
molecular nanomagnets, also known as single-molecule magnets (SMMs), suitable for …

Synthesis and characterization of non-isolated-pentagon-rule actinide endohedral metallofullerenes U@ C 1 (17418)-C76, U@ C 1 (28324)-C80, and Th@ C 1 …

W Cai, L Abella, J Zhuang, X Zhang… - Journal of the …, 2018 - ACS Publications
For the first time, actinide endohedral metallofullerenes (EMFs) with non-isolated-pentagon-
rule (non-IPR) carbon cages, U@ C80, Th@ C80, and U@ C76, have been successfully …

Endohedral metallofullerenes: New structures and unseen phenomena

W Shen, S Hu, X Lu - Chemistry–A European Journal, 2020 - Wiley Online Library
Endohedral metallofullerenes (EMFs), namely fullerenes with metallic species encapsulated
inside, represent an ideal platform to investigate metal–metal or metal–carbon interactions …

Zigzag Sc2C2 Carbide Cluster inside a [88]Fullerene Cage with One Heptagon, Sc2C2@Cs(hept)-C88: A Kinetically Trapped Fullerene Formed by C2 …

CH Chen, L Abella, MR Ceron… - Journal of the …, 2016 - ACS Publications
A non-isolated pentagon rule metallic carbide clusterfullerene containing a heptagonal ring,
Sc2C2@ C s (hept)-C88, was isolated from the raw soot obtained by electric arc …

Fullerenes: historical background, novel biological activities versus possible health risks

C Pesado-Gómez, JS Serrano-García… - Coordination Chemistry …, 2024 - Elsevier
C 60 fullerene is an allotropic molecule made up of sixty carbon atoms, which adopts a
quasi-spherical geometry with twenty hexagonal faces and twelve pentagonal faces. This …