Kinetic stability of metal–organic frameworks for corrosive and coordinating gas capture
Metal–organic frameworks (MOFs) have diverse applications involving the storage,
separation and sensing of weakly interacting, high-purity gases. Exposure to impure gas …
separation and sensing of weakly interacting, high-purity gases. Exposure to impure gas …
Metal–Organic Frameworks for NOx Adsorption and Their Applications in Separation, Sensing, Catalysis, and Biology
Nitrogen oxide (NOx) is a family of poisonous and highly reactive gases formed when fuel is
burned at high temperatures during anthropogenic behavior. It is a strong oxidizing agent …
burned at high temperatures during anthropogenic behavior. It is a strong oxidizing agent …
Elucidation of the Electrocatalytic Nitrite Reduction Mechanism by Bio-Inspired Copper Complexes
PH van Langevelde, S Engbers, F Buda… - ACS …, 2023 - ACS Publications
Mononuclear copper complexes relevant to the active site of copper nitrite reductases
(CuNiRs) are known to be catalytically active for the reduction of nitrite. Yet, their catalytic …
(CuNiRs) are known to be catalytically active for the reduction of nitrite. Yet, their catalytic …
Binding and activation of nitrite and nitric oxide by copper nitrite reductase and corresponding model complexes
AC Merkle, N Lehnert - Dalton Transactions, 2012 - pubs.rsc.org
The reduction of nitrite to nitric oxide in dissimilatory denitrification is carried out by copper
nitrite reductases (CuNIRs) via a type 2 copper site. Extended studies on CuNIRs in …
nitrite reductases (CuNIRs) via a type 2 copper site. Extended studies on CuNIRs in …
Thermal cycling of a MOF-based NO disproportionation catalyst
The metal–organic framework CuI-MFU-4 l reacts with NO, initially forming a copper (I)-
nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII …
nitrosyl at low pressure, and subsequently generates NO disproportionation products CuII …
A redox series of aluminum complexes: characterization of four oxidation states including a ligand biradical state stabilized via exchange coupling
Electrophilic activation and subsequent reduction of substrates is in general not possible
because highly Lewis acidic metals lack access to multiple redox states. Herein, we …
because highly Lewis acidic metals lack access to multiple redox states. Herein, we …
Nitrite reduction by copper through ligand-mediated proton and electron transfer
CM Moore, NK Szymczak - Chemical Science, 2015 - pubs.rsc.org
Nitrite reduction by a copper complex featuring a proton-responsive tripodal ligand is
demonstrated. Gaseous nitric oxide was confirmed as the sole NOX by-product in …
demonstrated. Gaseous nitric oxide was confirmed as the sole NOX by-product in …
Copper‐Catalyzed Monooxygenation of Phenols: Evidence for a Mononuclear Reaction Mechanism
R Schneider, TA Engesser, C Näther… - Angewandte Chemie …, 2022 - Wiley Online Library
Abstract The CuI salts [Cu (CH3CN) 4] PF and [Cu (oDFB) 2] PF with the very weakly
coordinating anion Al (OC (CF3) 3) 4−(PF) as well as [Cu (NEt3) 2] PF comprising the …
coordinating anion Al (OC (CF3) 3) 4−(PF) as well as [Cu (NEt3) 2] PF comprising the …
Nitrite and Nitric Oxide Interconversion at Mononuclear Copper (II): Insight into the Role of the Red Copper Site in Denitrification
BS Anju, NR Nair, S Kundu - … Chemie International Edition, 2023 - Wiley Online Library
Abstract Nitrite (NO2−) and nitric oxide (NO) interconversion is crucial for maintaining
optimum NO flux in mammalian physiology. Herein we demonstrate that [L2CuII (nitrite)]+ …
optimum NO flux in mammalian physiology. Herein we demonstrate that [L2CuII (nitrite)]+ …
T-Shaped Palladium and Platinum {MNO}10 Nitrosyl Complexes
The synthesis and characterization of a homologous series of T-shaped {MNO} 10 nitrosyl
complexes of the form [M (PR3) 2 (NO)]+(M= Pd, Pt; R= t Bu, Ad) are reported. These …
complexes of the form [M (PR3) 2 (NO)]+(M= Pd, Pt; R= t Bu, Ad) are reported. These …