Catalysts with metal-acid dual sites for selective hydrodeoxygenation of lignin derivatives: Progress in regulation strategies and applications

X Wang, Z Zhang, Z Yan, Q Li, Y Zhang - Applied Catalysis A: General, 2023 - Elsevier
Metal sites and acid sites in catalysts play an important role in promoting the
hydrodeoxygenation (HDO) of lignin derivatives. Herein, the review first summarizes the …

Vacancy Engineering in Transition Metal Sulfide and Oxide Catalysts for Hydrodeoxygenation of Lignin‐Derived Oxygenates

S Jiang, N Ji, X Diao, H Li, Y Rong, Y Lei… - ChemSusChem, 2021 - Wiley Online Library
The catalytic hydrodeoxygenation (HDO) of lignin has long been a hot research topic and
vacancy engineering is a new means to develop more efficient catalysts for this process …

Advances in understanding the selective hydrogenolysis of biomass derivatives

YS Yun, CE Berdugo-Díaz, DW Flaherty - ACS Catalysis, 2021 - ACS Publications
Biomass has attracted great attention as an alternative to petrochemicals for the production
of valuable chemicals and fuels. Hydrogenolysis reactions over heterogeneous catalysts …

Catalytic hydrodeoxygenation of lignin-derived oxygenates: catalysis, mechanism, and effect of process conditions

VS Prabhudesai, L Gurrala, R Vinu - Energy & Fuels, 2021 - ACS Publications
The high oxygen content of pyrolysis bio-oil with many organic functional groups in it limits
its direct application as a blendstock. The upgradation of biomass-derived oxygenates into …

Supported MoOx and WOx Solid Acids for Biomass Valorization: Interplay of Coordination Chemistry, Acidity, and Catalysis

P Sudarsanam, NK Gupta, B Mallesham, N Singh… - Acs …, 2021 - ACS Publications
Supported molybdenum oxide (MoO x) and tungsten oxide (WO x) materials are a vital class
of solid acid catalysts for the chemical industry because of their nontoxic nature, strong …

Hydrodeoxygenation of guaiacol to phenol over ceria-supported iron catalysts

C Li, Y Nakagawa, M Tamura, A Nakayama… - ACS …, 2020 - ACS Publications
Guaiacol, one of the main components and a model compound of lignin-derived bio-oil, was
transformed into phenol and methylated phenols over a series of supported iron catalysts …

Product‐oriented direct cleavage of chemical linkages in lignin

X Shen, Y Xin, H Liu, B Han - ChemSusChem, 2020 - Wiley Online Library
Lignin is one of the most important biomacromolecules in the plant biomass and the largest
renewable source of aromatic building blocks in nature. Selectively producing value‐added …

Kinetic Analysis of the Hydrodeoxygenation of Aliphatic Volatilized Lignin Molecules on Bulk MoO3: Elucidating the Formation of Alkenes and Alkanes

AJ Kohler, CH Walter, BH Shanks - ACS Catalysis, 2023 - ACS Publications
Universal oxygen removal of depolymerized lignin molecules is a desirable route to funnel
complex mixtures of bioderived molecules to high-demand “drop-in” petrochemical …

Catalyst Property Effects on Product Distribution during the Hydrodeoxygenation of Lignin Pyrolysis Vapors over MoO3/γ-Al2O3

A Saraeian, SJ Burkhow, D Jing, EA Smith… - ACS Sustainable …, 2021 - ACS Publications
Hydrodeoxygenation (HDO) of three model compounds (ie, anisole, 4-propylphenol, and 2-
butanone) and real lignin pyrolysis vapors was investigated at 673 K and∼ 1.7 bar of H2 …

Zeolitic Framework Ta and MoO3 Confined in Beta Zeolite Cooperatively Enhance Activity and Stability for Oxidative Desulfurization

Z Zhu, S Bo, X Wang, F Zuo, T Su, K Yang, H Lü - Langmuir, 2024 - ACS Publications
Oxidative desulfurization (ODS), as a novel desulfurization technique of fuel oil, possesses
high desulfurization efficiency for aromatic sulfide and low cost, making it a promising …