In this paper, the potential that organometallic architectures consisting of two transition metal
centers linked by an organic unsaturated spacer present for the study and development of …

The catalytic properties of several ruthenium, osmium and rhodium hydride complexes for
hydrogen/deuterium (H/D) exchange between olefins and deuterium oxide (D2O) were …

Treatment of RuHCl (CO)(PPh3) 3 with (E)-HC⋮ CCH CHC⋮ CH produces [RuCl
(CO)(PPh3) 2] 2 (μ-(E, E, E)-CH CHCH CHCH CH). The latter complex reacts with PMe3, 4 …

Reactions of HC⋮ CCH2CH (OR) CH (OR) CH2C⋮ CH (R= H, MeSO2) with RuHCl
(CO)(PPh3) 3 produced [RuCl (CO)(PPh3) 2] 2 (μ-CH CHCH2CH (OR) CH (OR) CH2CH …

Treatment of RuHCl (CO)(PPh3) 3 with (3 E, 5 E, 7 E)-HC⋮ CCH CHCH CHCH CHC⋮ CH
produces [RuCl (CO)(PPh3) 2] 2 (μ-CH CHCH CHCH CHCH CHCH CH). The latter complex …

Treatment of RuHCl (CO)(PPh3) 3 with 1, 3, 5-triethynylbenzene produces the trimetallic
complex 1, 3, 5-[Cl (CO)(PPh3) 2RuCH CH] 3C6H3, which reacts with PMe3 to give 1, 3, 5 …

Treatment of [CpOs (PPh3) 2] BF4 in THF with 0.5 equiv of HC⋮ CCH (OH) C⋮ CH followed
by Al2O3 gave the C5H-bridged compound [Cp (PPh3) 2Os CC CHC⋮ COs (PPh3) 2Cp] …

Reaction of Me3SiC⋮ CC⋮ CSiMe3 with RuHCl (CO)(PPh3) 3 in CH2Cl2 produced RuCl
(η1-C (C⋮ CSiMe3) CHSiMe3)(CO)(PPh3) 2, which on treatment with dppe gave RuCl (η1 …

The complex Fc (CH CH) 2C⋮ C-TMS (Fc= ferrocenyl) was obtained from Wittig olefination
of FcCH2PPh3Br with TMS-C⋮ CCH CHCHO in THF. The conjugated monometallic diene …

RhIII and IrIII can be complexed to bipyridine groups attached to the termini of bis
(dioxaborine)-capped heptamethines; these chromophores exhibit large third-order …