Theoretical insights into the substitution effect of phenanthroline derivatives on Am (III)/Eu (III) separation
XP Lei, QY Wu, CZ Wang, JH Lan, ZF Chai… - Inorganic …, 2023 - ACS Publications
Separation of trivalent actinides (An (III)) and lanthanides (Ln (III)) poses a huge challenge in
the reprocessing of spent nuclear fuel due to their similar chemical properties. N, N …
the reprocessing of spent nuclear fuel due to their similar chemical properties. N, N …
Does the length of the alkyl chain affect the complexation and selectivity of phenanthroline-derived phosphonate ligands?–Answers from DFT calculations
C Ebenezer, RV Solomon - Polyhedron, 2021 - Elsevier
The soft–hard-donor-combined phosphonate-based ligands are one of the popular
extractants for the separation of actinide from lanthanide in nuclear waste management …
extractants for the separation of actinide from lanthanide in nuclear waste management …
Chloride‐Induced Aufbau of Perchlorinated Cyclohexasilanes from Si2Cl6: A Mechanistic Scenario
J Tillmann, L Meyer, JI Schweizer… - … A European Journal, 2014 - Wiley Online Library
A surprisingly simple preparative procedure, addition of Si2Cl6 to a solution of [nBu4N] Cl in
CH2Cl2, leads to the formation of the chloride‐complexed cyclic dianions [Si6Cl12⋅ 2Cl] …
CH2Cl2, leads to the formation of the chloride‐complexed cyclic dianions [Si6Cl12⋅ 2Cl] …
Theoretical evaluation of mixed N-, O-donor based TMPhenDA ligand in selective complexation with actinide (III) ions over lanthanide (III) ions
Separation of trivalent actinides An (III) from lanthanide Ln (III) is an extremely challenging
task in handling nuclear wastes due to their similar chemical behaviours. Though many …
task in handling nuclear wastes due to their similar chemical behaviours. Though many …
Silicon chemistry in zero to three dimensions: from dichlorosilylene to silafullerane
J Teichmann, M Wagner - Chemical Communications, 2018 - pubs.rsc.org
Silylenes and silanides, prominent Si (II) species, are not only interesting in their own right,
but also constitute important building blocks in oligosilane and organosilane chemistry. The …
but also constitute important building blocks in oligosilane and organosilane chemistry. The …
Selective complexation of trivalent americium over europium with substituted Triazolebipyridine-based ligand in high Level-Liquid Waste-A DFT Investigation
C Ebenezer, RV Solomon - Polyhedron, 2022 - Elsevier
Similar chemical properties like ionic radius and oxidation states exhibited by trivalent
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
A twelve-coordinated iodide in a cuboctahedral silver (I) skeleton
JH Liao, C Latouche, B Li, S Kahlal… - Inorganic …, 2014 - ACS Publications
Three new halide-centered octanuclear silver (I) complexes,[Ag8 (X){S2P (CH2CH2Ph) 2}
6](PF6), X= F–, 1; Cl–, 2; Br–, 3; were prepared in the presence of the corresponding halide …
6](PF6), X= F–, 1; Cl–, 2; Br–, 3; were prepared in the presence of the corresponding halide …
Preorganization of N, O-hybrid phosphine oxide chelators for effective extraction of trivalent Am/Eu ions–a computational study
C Ebenezer, RV Solomon - New Journal of Chemistry, 2022 - pubs.rsc.org
N, O-Hybrid phosphine oxide ligands with N-heterocyclic cores are advanced extractants for
extracting actinides over lanthanides. However, the challenging task in designing an …
extracting actinides over lanthanides. However, the challenging task in designing an …
Insights into the Extraction of Actinides from Lanthanides Using 3, 3'‐Dimethoxy‐phenyl‐bis‐1, 2, 4‐triazinyl‐2, 6‐pyridine Ligand–A DFT Study
C Ebenezer, RV Solomon - ChemistrySelect, 2020 - Wiley Online Library
Abstract Recently reported 3, 3'‐dimethoxy‐phenyl‐bis‐1, 2, 4‐triazinyl‐2, 6‐pyridine
(DMOP‐BTP) ligand is recognized as an efficient candidate for the stripping of actinides (An) …
(DMOP‐BTP) ligand is recognized as an efficient candidate for the stripping of actinides (An) …
[PDF][PDF] Selective complexation of trivalent americium over europium with substituted Triazolebipyridine-based ligand in high Level-Liquid Waste-A DFT Investigation
C Ebenezer, RV Solomon - Polyhedron, 2022 - drive.google.com
Similar chemical properties like ionic radius and oxidation states exhibited by trivalent
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …
actinides (An (III)) and lanthanides (Ln (III)) pose a challenge for their separation in …