1. INTRODUCTION This review article is concerned with the use of compounds 1 and 2
(Figure 1) as effective and very versatile reagents for trifluoromethylation reactions of a …

Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

Fluorine, often called as “a small atom with a big ego”, 1 lies in the second row and the 17th
column in the periodic table of the chemical elements. This unique position in the periodic …

Fluorinated organic compounds increasingly gain importance in numerous areas of
chemistry and everyday life. Building blocks which contain fluorinated entities are of high …

The trifluoromethyl group is found in many synthetic bioactive compounds, and the
difunctionalization of a C C bond, as a powerful strategy for the construction of compounds …

This review summarizes the recent progress the emerging area of photochemical reaction
initiated by Electron-donor-acceptor (EDA) complex in synthetic organic chemistry. Recent …

The mechanisms of most organic reactions are considered to proceed by two-electron
transfer pathways, even though both biology and radical chemistry rely extensively on one …

Electrophilic trifluoromethylation reactions have been the latest approach to achieve the
fluoroalkylation of compounds with newly‐discovered reagents, such as the Togni's (1 …

The direct trifluoromethylation of (hetero) arenes is a process of high importance to the
pharmaceutical industry. Many reagents exist for this purpose and have found widespread …

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described.
The production of perfluoroalkyl radicals (RF= C n F2 n+ 1, n≥ 2), which effect both addition …