Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications
A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …
Chemistry of compounds based on 1, 2, 3-triazolylidene-type mesoionic carbenes
Mesoionic carbenes (MICs) of the 1, 2, 3-triazolylidene type have established themselves as
a popular class of compounds over the past decade. Primary reasons for this popularity are …
a popular class of compounds over the past decade. Primary reasons for this popularity are …
Pushing Electrons Which Carbene Ligand for Which Application?
D Munz - Organometallics, 2018 - ACS Publications
This tutorial explores the diversity and characteristics of C-donor ligands. Particular
emphasis is put on the conceptual design of the electronic properties for applications in …
emphasis is put on the conceptual design of the electronic properties for applications in …
Not All 3MC States Are the Same: The Role of 3MCcis States in the Photochemical N∧N Ligand Release from [Ru(bpy)2(N∧N)]2+ Complexes
K Eastham, PA Scattergood, D Chu, RZ Boota… - Inorganic …, 2022 - ACS Publications
Ruthenium (II) complexes feature prominently in the development of agents for
photoactivated chemotherapy; however, the excited-state mechanisms by which …
photoactivated chemotherapy; however, the excited-state mechanisms by which …
Rhenium Complexes of Pyridyl-Mesoionic Carbenes: Photochemical Properties and Electrocatalytic CO2 Reduction
L Suntrup, F Stein, J Klein, A Wilting… - Inorganic …, 2020 - ACS Publications
Mesoionic carbenes have found wide use as components of homogeneous catalysts.
Recent discoveries have, however, shown that metal complexes of such ligands also have …
Recent discoveries have, however, shown that metal complexes of such ligands also have …
Bis-Triazolylidenes of Manganese and Rhenium and Their Catalytic Application in N-Alkylation of Amines with Alcohols
A new family of air-stable Mn and Re complexes bearing bidentate bis (1, 2, 3-triazol-5-
ylidene) ligands with the general formula [M (bis-triazolylidene)(CO) 3X](M= Mn or Re; X= Cl …
ylidene) ligands with the general formula [M (bis-triazolylidene)(CO) 3X](M= Mn or Re; X= Cl …
An unexpected journey from highly tunable phosphorescence to novel photochemistry of 1, 2, 3-triazole-based complexes
PA Scattergood, PIP Elliott - Dalton Transactions, 2017 - pubs.rsc.org
The photophysical properties of transition metal complexes have long attracted interest in
the literature with significant research activity during the past two to three decades due to the …
the literature with significant research activity during the past two to three decades due to the …
Chromium (0) and Molydenum (0) Complexes with a Pyridyl-Mesoionic Carbene Ligand: Structural,(Spectro) electrochemical, Photochemical, and Theoretical …
T Bens, P Boden, P Di Martino-Fumo… - Inorganic …, 2020 - ACS Publications
This work reports on the synthesis and in-depth electrochemical and photochemical
characterization of two chromium (0) and molydenum (0) metal complexes with bidentate …
characterization of two chromium (0) and molydenum (0) metal complexes with bidentate …
Probing Electronic Properties of Triazolylidenes through Mesoionic Selones, Triazolium Salts, and Ir-Carbonyl-Triazolylidene Complexes
J Beerhues, H Aberhan, TN Streit, B Sarkar - Organometallics, 2020 - ACS Publications
Understanding and quantifying the electronic properties of ligands is important both from a
fundamental point of view and also for their applications in various branches of chemistry. In …
fundamental point of view and also for their applications in various branches of chemistry. In …
New 1, 2, 3-triazole based bis-and trisphosphine ligands: synthesis, transition metal chemistry and catalytic studies
L Radhakrishna, HS Kunchur, PK Namdeo… - Dalton …, 2020 - pubs.rsc.org
The syntheses and transition metal chemistry of triazole-based bis-and tris-phosphines, 5-
(diphenylphosphanyl)-1-(2-(diphenylphosphanyl) phenyl)-4-phenyl-1H-1, 2, 3-triazole (2), 5 …
(diphenylphosphanyl)-1-(2-(diphenylphosphanyl) phenyl)-4-phenyl-1H-1, 2, 3-triazole (2), 5 …