Catalytic Alkyne Allylboration: A Quest for Selectivity

A Chaves-Pouso, E Rivera-Chao… - ACS catalysis, 2023 - ACS Publications
Catalytic methodologies that enable the synthesis of complex organic molecules from simple
and readily available starting materials represent a goal in modern synthetic chemistry. In …

[HTML][HTML] Updated Progress of the Copper-Catalyzed Borylative Functionalization of Unsaturated Molecules

B Li, H Liang, A Vignesh, X Zhou, Y Liu, Z Ke - Molecules, 2023 - mdpi.com
Borylation has become a powerful method to synthesize organoboranes as versatile
building blocks in organic synthesis, medicinal chemistry, and materials science. Copper …

Facile and General Electrochemical Diselenylation of Terminal Alkynes

P Zhou, H Jiao, K Niu, H Song, Y Liu… - … Sustainable Chemistry & …, 2023 - ACS Publications
Difunctionalization of terminal alkynes is a cutting-edge method for producing trisubstituted
alkenes. The methods employed, however, rely heavily on the use of organometallic species …

Boranes Paving the Way to Anionic Cyclic (Alkyl)(amino) carbenes (Ani‐cAACs)

L Zapf, S Peters, U Radius… - Angewandte Chemie …, 2023 - Wiley Online Library
First examples of anionic cyclic (alkyl)(amino) carbenes (Ani‐cAACs) that contain borane
substituents have been synthesized. The nature of the borane substituents allows a …

A Straightforward Access to Cyclic (Alkyl)(amino) carbene Copper (I) Complexes

J Lorkowski, MR Serrato, M Gembicki… - European Journal of …, 2023 - Wiley Online Library
A Straightforward Access to Cyclic (Alkyl)(amino)carbene Copper (I) Complexes - Lorkowski
- 2023 - European Journal of Inorganic Chemistry - Wiley Online Library Skip to Article …

[HTML][HTML] Regioselective catalytic carbonylation and borylation of alkynes with aryldiazonium salts toward α-unsubstituted β-boryl ketones

F Zhu, P Yin, XF Wu - Chemical Science, 2022 - pubs.rsc.org
A new Pd/Cu-catalyzed carbonylation and borylation of alkynes with aryldiazonium salts
toward α-unsubstituted β-boryl ketones with complete regioselectivity has been developed …

Regio- and Stereoselective Intermolecular Oxysulfonylation of Alkynes with 1,3-Diketones to Access (Z)-β-Sulfonated Enethers

D Bhadoria, R Kumar, R Kant… - The Journal of Organic …, 2023 - ACS Publications
The first multicomponent regio-and stereoselective difunctionalization of alkynes via
concomitant C–O and C–S bond formation using 1, 3-diketones and sodium sulfinate has …

Modulation of Lewis Acidity and Steric Parameters in Cyclic Boronates: Copper-Catalyzed Internal-Selective Borylation of Challenging Terminal Alkynes

T Tsushima, M Nakamoto, H Yoshida - ACS Catalysis, 2024 - ACS Publications
The installation of a boron functionality into a more substituted carbon of terminal alkynes in
copper-catalyzed borylations with diborons is still a challenging subject, primarily due to the …

The boration reaction using B2pai2

C Niu, Q Li, C Zhang - Tetrahedron, 2023 - Elsevier
Boration reaction is a hot topic in the research field of organic synthesis. Undoubtedly, the
diboron reagents, which are stable and easily available starting materials, are widely used …

Ring-expanded N-heterocyclic carbene (reNHC) complexes: Applications in transition metal catalysis

T Zhou, G Utecht-Jarzyńska, M Szostak - Coordination Chemistry Reviews, 2024 - Elsevier
In the past two decades, NHCs (NHC= N-heterocyclic carbenes) have emerged as one of
the most important classes of ligands in transition metal catalysis. Although historically 5 …