Recent Advances in Solid‐State Lighting Devices Using Transition Metal Complexes Exhibiting Thermally Activated Delayed Fluorescent Emission Mechanism

GU Mahoro, J Fernandez‐Cestau… - Advanced Optical …, 2020 - Wiley Online Library
This review focuses on the state‐of‐the‐art of solid‐state lighting devices (SSLDs)—that is,
organic light‐emitting diodes (OLEDs) and light‐emitting electrochemical cells (LECs) …

Crystalline metal‐organic materials with thermally activated delayed fluorescence

Z Han, XY Dong, SQ Zang - Advanced Optical Materials, 2021 - Wiley Online Library
Thermally activated delayed fluorescence (TADF) properties of crystalline metal‐organic
materials, mainly including small‐molecule metal–organic complexes, organic ligand …

Stimulus‐Triggered Formation of an Anion–Cation Exciplex in Copper (I) Complexes as a Mechanism for Mechanochromic Phosphorescence

B Hupp, J Nitsch, T Schmitt… - Angewandte Chemie …, 2018 - Wiley Online Library
The investigation of the mechanisms of mechanochromic luminescence is of fundamental
importance for the development of materials for photonic sensors, data storage, and …

Linear Carbene Pyridine Copper Complexes with Sterically Demanding N,N′-Bis(trityl)imidazolylidene: Syntheses, Molecular Structures, and Photophysical …

T Hölzel, A Belyaev, M Terzi, L Stenzel… - Inorganic …, 2021 - ACS Publications
The sterically demanding carbene ITr (N, N′-bis (triphenylmethyl) imidazolylidene) was
used as a ligand for the preparation of luminescent copper (I) complexes of the type [(ITr) Cu …

Dicopper (I) paddle-wheel complexes with thermally activated delayed fluorescence adjusted by ancillary ligands

AV Artem'ev, MP Davydova, AS Berezin… - Inorganic …, 2020 - ACS Publications
A suite of paddle-wheel shaped [Cu2 (PymPPh2) 3 (Lan) n](PF6) 2 complexes showing
efficient thermally activated delayed fluorescence (TADF) has been synthesized. In these …

Keep it tight: a crucial role of bridging phosphine ligands in the design and optical properties of multinuclear coinage metal complexes

AV Paderina, IO Koshevoy, EV Grachova - Dalton Transactions, 2021 - pubs.rsc.org
Copper subgroup metal ions in the+ 1 oxidation state are classical candidates for
aggregation via non-covalent metal–metal interactions, which are supported by a number of …

Luminescent mechanochromic dinuclear Cu (I) complexes with macrocyclic diamine-tetracarbene ligands

T Lu, JY Wang, D Tu, ZN Chen, XT Chen… - Inorganic …, 2018 - ACS Publications
Dinuclear Cu (I) complexes bearing hexadentate, macrocyclic N-heterocyclic carbene
(NHC) ligands,[Cu2 (L1)(CH3CN)][PF6] 2 (1) and [Cu2 (L2)(CH3CN)] 2 [Cu2 (L2)(CH3CN) …

Oligophosphine-thiocyanate copper (I) and silver (I) complexes and their borane derivatives showing delayed fluorescence

G Chakkaradhari, T Eskelinen, C Degbe… - Inorganic …, 2019 - ACS Publications
The series of chelating phosphine ligands, which contain bidentate P 2 (bis [(2-
diphenylphosphino) phenyl] ether, DPEphos; 4, 5-bis (diphenylphosphino)-9, 9 …

Selective coordination of coinage metals using orthogonal ligand scaffolds

VR Naina, F Krätschmer, PW Roesky - Chemical Communications, 2022 - pubs.rsc.org
Group 11 metal complexes with their ability to form metallophilic interations are widely
pursued to develop multifunctional luminescent materials. Heteronuclear coinage metal …

Excitation‐Wavelength‐Dependent Emission and Delayed Fluorescence in a Proton‐Transfer System

AS Berezin, KA Vinogradova… - … A European Journal, 2018 - Wiley Online Library
Manipulating the relaxation pathways of excited states and understanding mechanisms of
photochemical reactions present important challenges in chemistry. Here we report a unique …