Hydroformylation is the addition of synthesis gas (“syngas”), a mixture of CO and H2, to
olefins in the presence of a catalyst under the formation of aldehydes. Hydrogen (“hydro”) …

The “phenylpropenoids” are a well-known set of naturally occurring compounds obtained
mainly from plant sources. 1, 2 Of this group, the generalized 2-propenylbenzenes 1 and 1 …

In the last decade there have been numerous advances in the area of rhodium-catalyzed
hydroformylation, such as highly selective catalysts of industrial importance, new insights …

A highly chemo-and regioselective hydroaminomethylation of simple as well as
functionalized α-olefins using a cationic rhodium precatalyst together with Xantphos as …

Abstract Metal (Co, Rh, Pt/Sn)‐catalyzed homogeneous hydroformylation reactions produce
aldehydes, acetals, and alcohols, respectively, which are important aroma compounds that …

In the last four decades, one of the most important advances in organometallic catalysis has
been the use of molecular catalysts in two-phase liquid-liquid systems, commonly known as …

Asymmetric hydroheteroarylation of alkenes represents a convenient entry to elaborated
heterocyclic motifs. While chiral acids are known to mediate asymmetric addition of electron …

A one-pot two-step approach for the synthesis of diacetate esters from propenylphenols was
developed. This protocol involves the functionalization of the propenylphenol in two remote …

We report a catalytic system comprised of nitrogen-centered di-or triphosphine ligands in
conjunction with rhodium that is capable of delivering branched aldehydes from terminal …

The use of biomass as a new platform of chemical substrates has become a subject of
intensive research. In this sense, allylbenzenes and their isomeric analogues represent an …