Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies

XH Ding, YZ Chang, CJ Ou, JY Lin… - National Science …, 2020 - academic.oup.com
Halogen bonding is emerging as a significant driving force for supramolecular self-assembly
and has aroused great interest during the last two decades. Among the various halogen …

Enhancing supramolecular assembly in bodipy derivatives: harnessing halogen bonding for cocrystal design

G Gümüşgöz Çelik, B Dedeoglu… - Crystal Growth & …, 2023 - ACS Publications
Supramolecular synthesis, a field of study in chemistry, offers a versatile approach to
construct complex structures using non-covalent interactions. In this study, we explore the …

Two and three-dimensional halogen-bonded frameworks: self-assembly influenced by crystallization solvents

CZ Liu, JJ Wang, B Yang, ZY Li, M Yan… - Chemical …, 2023 - pubs.rsc.org
In this paper, two types of solid phase 2D and 3D XBOFs were selectively constructed from
identical building blocks of tetraphenylmethane tetrapyridine derivative and 1, 4 …

Modulation of metallophilic and π–π interactions in platinum cyclometalated luminophores with halogen bonding

V Sivchik, A Kochetov, T Eskelinen… - … A European Journal, 2021 - Wiley Online Library
Luminescent cyclometalated complexes [M (C^ N^ N) CN](M= Pt, Pd; HC^ N^ N= pyridinyl‐
(M= Pt 1, Pd 5), benzyltriazolyl‐(M= Pt 2), indazolyl‐(M= Pt 3, Pd 6), pyrazolyl …

Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1, 4-diiodotetrafluorobenzene

V Nemec, L Fotović, T Vitasović, D Cinčić - CrystEngComm, 2019 - pubs.rsc.org
Halogen bonding of the aldehyde oxygen atom in cocrystals of aromatic aldehydes and 1,4-diiodotetrafluorobenzene
- CrystEngComm (RSC Publishing) DOI:10.1039/C9CE00340A Royal Society of Chemistry …

Simple design for metal-based halogen-bonded cocrystals utilizing the M–Cl⋯ I motif

K Lisac, D Cinčić - CrystEngComm, 2018 - pubs.rsc.org
We demonstrate a strategy for synthesizing halogen-bonded metal–organic cocrystals by
utilizing metal complexes whose pendant chloride group enables halogen bonding. A series …

Supramolecular networks by imine halogen bonding

E Nieland, D Komisarek, S Hohloch, K Wurst… - Chemical …, 2022 - pubs.rsc.org
Halogen bonding of neutral donors using imine groups of porous organic cage compounds
as acceptors leads to the formation of halogen-bonded frameworks. We report the use of two …

Isothiocyanate Sulfur Atom as an Acceptor Site for Halogen-Bonded Cocrystallization of Werner Ni (II) Coordination Compounds and Perfluorinated Iodobenzenes

L Posavec, D Cinčić - Crystal growth & design, 2024 - ACS Publications
We explore the halogen bond acceptor potential of the isothiocyanate sulfur atom in the
synthesis of cocrystals involving metal–organic building blocks by using Werner Ni (II) …

Anion templated crystal engineering of halogen bonding tripodal tris (halopyridinium) compounds

ÉM Foyle, NG White - CrystEngComm, 2020 - pubs.rsc.org
In this work four new tripodal tris (halopyridinium) receptors containing potentially halogen
bonding groups were prepared. The ability of the receptors to bind anions in competitive …