Recent advances in transition-metal-catalyzed carbene insertion to C–H bonds

Y He, Z Huang, K Wu, J Ma, YG Zhou… - Chemical Society Reviews, 2022 - pubs.rsc.org
C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

1, 2, 3-Triazole and its analogues: new surrogates for diazo compounds

M Akter, K Rupa, P Anbarasan - Chemical Reviews, 2022 - ACS Publications
Readily accessible and shelf-stable 1, 2, 3-triazole and its analogues such as pyridotriazole,
triazoloindole, benzotriazole, and thiadiazole exist in equilibrium with their ring-opened …

Comprehensive strategies for the synthesis of isoquinolines: Progress Since 2008

R Gujjarappa, N Vodnala… - Advanced Synthesis & …, 2020 - Wiley Online Library
In the past decades, an enormous number of reports have been dedicated towards the
synthesis of nitrogen containing heterocycles. This immense interest have emerged owing to …

Regiocontrol in the oxidative Heck reaction of indole by ligand-enabled switch of the regioselectivity-determining step

YJ Wang, CH Yuan, DZ Chu, L Jiao - Chemical Science, 2020 - pubs.rsc.org
Efficient control of regioselectivity is a key concern in transition-metal-catalyzed direct C–H
functionalization reactions. Various strategies for regiocontrol have been established by …

Catalytic Insertion Reactions of α‐Imino Carbenoids

K Pal, CMR Volla - The Chemical Record, 2021 - Wiley Online Library
Over the past decade, α‐imino carbenoids generated via transition metal (such as rhodium,
nickel, copper, palladium, silver) catalyzed denitrogenative ring‐opening of N‐sulfonyl‐1, 2 …

Application of Transition Metal‐Catalyzed C− H Activation Strategies in the Synthesis and Functionalization of β‐Carbolines

KS Riyazahmed, D Bora… - Asian Journal of Organic …, 2021 - Wiley Online Library
Abstract β‐Carboline and its derivatives are well‐known for their biological and
pharmacological properties and are considered as an important source of drug or drug …

Synthesis of 3-Alkoxy-4-Pyrrolin-2-ones via Rhodium(II)-Catalyzed Denitrogenative Transannulation of 1H-1,2,3-Triazoles with Diazo Esters

AN Koronatov, NV Rostovskii, AF Khlebnikov… - Organic …, 2020 - ACS Publications
A method for the synthesis of densely substituted 4-pyrrolin-2-ones by Rh (II)-catalyzed
denitrogenative transannulation of 1-alkyl-4-aryl-1 H-1, 2, 3-triazoles with diazo esters has …

Catalytic Functionalization of Metallocarbenes Derived from α‐Diazocarbonyl Compounds and Their Precursors

D Yadagiri, P Anbarasan - The Chemical Record, 2021 - Wiley Online Library
Short and efficient synthesis of heterocyclic compounds are highly desirable in synthetic
organic chemistry. It is a dream approach to accomplish these syntheses from readily …

Recent Advances in the Synthesis of 5‐Membered N‐Heterocycles via Rhodium Catalysed Cascade Reactions

DR Mishra, BS Panda, S Nayak, J Panda… - …, 2022 - Wiley Online Library
Five membered N‐heterocycles are significant targets in organic synthesis because of their
ubiquitous existence in bioactive natural products and pharmaceuticals. Over the past …

Palladium/Copper-Catalyzed Denitrogenative Alkylidenation and ortho-Alkynylation Reaction of 1,2,3-Benzotriazin-4(3H)-ones

M Hari Balakrishnan, S Mannathan - Organic letters, 2019 - ACS Publications
An efficient palladium-catalyzed approach to access various functionalized (Z)-3-
benzylidene-isoindoline-1-ones and (Z)-3-benzylidene (imino) isobenzofuranones via a …