Nickel's+ 1 oxidation state has received much interest due to its varied and often enigmatic
behavior in increasingly popular catalytic methods. In part, the lack of understanding about …

Metallaphotoredox catalysis can unlock useful pathways for transforming organic reactants
into desirable products, largely due to the conversion of photon energy into chemical …

Dual IrIII/LnNiII metallaphotoredox catalyzed C (sp3)–C (sp2) cross-coupling reactions are
widely assumed to proceed by photoinduced single electron transfer steps due to the highly …

Owing to their light-harvesting properties, nickel–bipyridine (bpy) complexes have found
wide use in metallaphotoredox cross-coupling reactions. Key to these transformations are Ni …

Transition-metal photoredox catalysis has transformed organic synthesis by harnessing light
to construct complex molecules. Nickel (II)–bipyridine (bpy) aryl halide complexes are a …

Within the context of Ni photoredox catalysis, halogen atom photoelimination from Ni has
emerged as a fruitful strategy for enabling hydrogen atom transfer (HAT)-mediated C (sp3) …

Ni II (IB) dihalide [IB=(3a R, 3a′ R, 8a S, 8a′ S)-2, 2′-(cyclopropane-1, 1-diyl) bis (3a, 8a-
dihydro-8 H-indeno [1, 2-d]-oxazole)] complexes are representative of a growing class of first …

This manuscript details the development of an asymmetric variant for the Ni-photoredox α-
arylation of tetrahydrofuran (THF), which was originally reported in a racemic fashion by …

A nickel complex of chiral bisoxazolines catalyzed the stereoselective reductive arylation of
ketones in high enantioselectivity. A range of common acyclic and cyclic ketones reacted …

The alkyne motif is present in several naturally occurring molecules and specialty chemicals.
The Sonogashira reaction is recognized as one of the most exploited methods for the …