Light-controlled radical polymerization: mechanisms, methods, and applications
M Chen, M Zhong, JA Johnson - Chemical reviews, 2016 - ACS Publications
The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …
strategy for rational polymer synthesis and advanced materials fabrication. This review …
Photoinduced electron transfer reactions for macromolecular syntheses
S Dadashi-Silab, S Doran, Y Yagci - Chemical reviews, 2016 - ACS Publications
Photochemical reactions, particularly those involving photoinduced electron transfer
processes, establish a substantial contribution to the modern synthetic chemistry, and the …
processes, establish a substantial contribution to the modern synthetic chemistry, and the …
Photomediated controlled radical polymerization
Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …
mild conditions, various well-defined polymers with complex architecture, such as block and …
Externally controlled atom transfer radical polymerization
Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …
Photopolymerization upon LEDs: new photoinitiating systems and strategies
C Dietlin, S Schweizer, P Xiao, J Zhang… - Polymer …, 2015 - pubs.rsc.org
This paper is focused on:(i) the recent developments in LED technology, allowing the design
of novel and efficient light sources for the free radical and cationic photopolymerization of …
of novel and efficient light sources for the free radical and cationic photopolymerization of …
Role of external field in polymerization: mechanism and kinetics
The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …
polymerization techniques subjected to external fields. Various physical modulations, such …
Light‐Regulated Polymerization under Near‐Infrared/Far‐Red Irradiation Catalyzed by Bacteriochlorophyll a
Photoregulated polymerizations are typically conducted using high‐energy (UV and blue)
light, which may lead to undesired side reactions. Furthermore, as the penetration of visible …
light, which may lead to undesired side reactions. Furthermore, as the penetration of visible …
Recent advances on coumarin-based photoinitiators of polymerization
F Dumur - European Polymer Journal, 2022 - Elsevier
During the past decades, a breakthrough has been obtained in the development of
photoinitiators activable under low light intensity and in the visible range. In the search for …
photoinitiators activable under low light intensity and in the visible range. In the search for …
Switchable polymerization catalysts
The intrinsic physical properties and functionalities displayed by synthetic polymers are
directly correlated to their respective microstructures. For example, complex biopolymers …
directly correlated to their respective microstructures. For example, complex biopolymers …
Selective photoactivation: from a single unit monomer insertion reaction to controlled polymer architectures
Here, we exploit the selectivity of photoactivation of thiocarbonylthio compounds to
implement two distinct organic and polymer synthetic methodologies:(1) a single unit …
implement two distinct organic and polymer synthetic methodologies:(1) a single unit …