The use of light to mediate controlled radical polymerization has emerged as a powerful
strategy for rational polymer synthesis and advanced materials fabrication. This review …

Photochemical reactions, particularly those involving photoinduced electron transfer
processes, establish a substantial contribution to the modern synthetic chemistry, and the …

Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …

Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

This paper is focused on:(i) the recent developments in LED technology, allowing the design
of novel and efficient light sources for the free radical and cationic photopolymerization of …

The past decades have witnessed an increasing interest in developing advanced
polymerization techniques subjected to external fields. Various physical modulations, such …

Photoregulated polymerizations are typically conducted using high‐energy (UV and blue)
light, which may lead to undesired side reactions. Furthermore, as the penetration of visible …

During the past decades, a breakthrough has been obtained in the development of
photoinitiators activable under low light intensity and in the visible range. In the search for …

The intrinsic physical properties and functionalities displayed by synthetic polymers are
directly correlated to their respective microstructures. For example, complex biopolymers …

Here, we exploit the selectivity of photoactivation of thiocarbonylthio compounds to
implement two distinct organic and polymer synthetic methodologies:(1) a single unit …