Electro-/photocatalytic alkene-derived radical cation chemistry: recent advances in synthetic applications

MJ Luo, Q Xiao, JH Li - Chemical Society Reviews, 2022 - pubs.rsc.org
Alkene-derived radical cations are versatile reactive intermediates and have been widely
applied in the construction of complex functionalized molecules and cyclic systems for …

Visible‐light photocatalysis: does it make a difference in organic synthesis?

L Marzo, SK Pagire, O Reiser… - Angewandte Chemie …, 2018 - Wiley Online Library
Visible‐light photocatalysis has evolved over the last decade into a widely used method in
organic synthesis. Photocatalytic variants have been reported for many important …

A general approach to catalytic alkene anti-Markovnikov hydrofunctionalization reactions via acridinium photoredox catalysis

KA Margrey, DA Nicewicz - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus The development of methods for anti-Markovnikov alkene
hydrofunctionalization has been a focal point of catalysis research for several decades. The …

Catalytic transformations of functionalized cyclic organic carbonates

W Guo, JE Gómez, À Cristòfol, J Xie… - Angewandte Chemie …, 2018 - Wiley Online Library
Functionalized cyclic organic carbonates and related heterocycles have emerged as highly
versatile heterocyclic substrates for ring‐opening and decarboxylative catalytic …

Photokatalyse mit sichtbarem Licht: Welche Bedeutung hat sie für die organische Synthese?

L Marzo, SK Pagire, O Reiser, B König - Angewandte Chemie, 2018 - Wiley Online Library
Abstract Die Photokatalyse mit sichtbarem Licht hat sich im letzten Jahrzehnt zu einer breit
angewandten Methode in der organischen Synthese entwickelt. Für viele wichtige …

Selectivity Control by Relay Catalysis in CO and CO2 Hydrogenation to Multicarbon Compounds

K Cheng, Y Li, J Kang, Q Zhang… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The hydrogenative conversion of both CO and CO2 into high-value multicarbon
(C2+) compounds, such as olefins, aromatic hydrocarbons, ethanol, and liquid fuels, has …

Efficient visible light photocatalysis of [2+ 2] enone cycloadditions

MA Ischay, ME Anzovino, J Du… - Journal of the American …, 2008 - ACS Publications
We report that Ru (bipy) 3Cl2 can serve as a visible light photocatalyst for [2+ 2] enone
cycloadditions. A variety of aryl enones participate readily in the reaction, and the …

Mechanistic insight into the photoredox catalysis of anti-markovnikov alkene hydrofunctionalization reactions

NA Romero, DA Nicewicz - Journal of the American Chemical …, 2014 - ACS Publications
We describe our efforts to understand the key mechanistic aspects of the previously reported
alkene hydrofunctionalization reactions using 9-mesityl-10-methylacridinium (Mes-Acr+) as …

Anti-Markovnikov hydrochlorination and hydronitrooxylation of α-olefins via visible-light photocatalysis

J Kim, X Sun, BA van der Worp, T Ritter - Nature Catalysis, 2023 - nature.com
Conventional hydrofunctionalization of α-olefins with mineral acids proceeds with
Markovnikov selectivity to afford branched isomers. The direct formation of linear …

A Photosensitizing Metal–Organic Framework as a Tandem Reaction Catalyst for Primary Alcohols from Terminal Alkenes and Alkynes

XC Lin, YM Wang, X Chen, PY You… - Angewandte Chemie …, 2023 - Wiley Online Library
Owing to the wide and growing demand for primary alcohols, the development of efficient
catalysts with high regioselectivity remains a worthwhile pursuit. However, according to …