Complexes of “late” transition metals of the 3d row based on functionalized o-iminobenzoquinone type ligands: Interrelation of molecular and electronic structure …

KI Pashanova, AI Poddel'sky, AV Piskunov - Coordination Chemistry …, 2022 - Elsevier
The present review covers the coordination compounds of the “late” transition metals of the
3d row (Mn, Fe, Co, Ni, Cu) based on sterically hindered functionalized o …

Specific features of spin, charge, and orbital ordering in cobaltites

BI Natal'ya, SG Ovchinnikov, MM Korshunov… - Physics …, 2009 - iopscience.iop.org
Complex cobalt oxides known as cobaltites are reviewed, including LnCoO 3-based
perovskite-structured rare-earth cobaltites (where Ln is lanthanum or a lanthanide), quasi …

Intermediate-spin state of a 3d ion in the octahedral environment and generalization of the tanabe–sugano diagrams

KV Lamonova, ES Zhitlukhina, RY Babkin… - The Journal of …, 2011 - ACS Publications
Electronic spectra of 3d n transition ions in an octahedral ligand surrounding have been
studied using the modified crystal field approach (MCFA), which includes a relativistic spin …

Spin state transformations of a 3d ion in the pyramidal environment and under lattice distortions

ES Zhitlukhina, KV Lamonova, SM Orel… - Journal of Physics …, 2007 - iopscience.iop.org
Spin state (SS) transitions in metal-containing pyramidal complexes that originate from
crystallographic distortions are the research subject of this work. The transition elements are …

[HTML][HTML] Modified crystal field theory and its applications

KV Lamonova, SM Orel, YG Pashkevich - Kyiv Akad, 2019 - akademperiodyka.org.ua
A new original approach to the study of coordination complexes with pa ra mag netic ions,
the modified crystal field theory (MCFT), is represented in the monograph. The approach is …

Spectroscopic evidence of spinel phase clustering in solid solutions Hg1− xCrxSe (0.03≤ x≤ 0.1)

K Lamonova, I Ivanchenko, S Orel… - Journal of Physics …, 2009 - iopscience.iop.org
The diluted magnetic semiconductors Hg 1− x Cr x Se (0.03≤ x≤ 0.1) were prepared by the
solid state recrystallization method. The structure microanalysis of the Hg 1− x Cr x Se …

Spin states of cobalt and the thermodynamics of Sm1 − x Ca x CoO3 − δ solid solutions

TN Vasil'chikova, TG Kuz'mova, AA Kamenev… - JETP letters, 2013 - Springer
In the rare-earth SmCoO 3 perovskite, Co 3+ ions at low temperatures appear to be in the
low-spin state with S= 0, t 2 g 2 eg 0. If Ca 2+ ions partially substitute Sm 3+ ions, oxygen …

Magnetic properties of Ce3+ ion in iron-containing oxypnictide CeFeAsO

OV Gornostaeva, KV Lamonova, SM Orel… - Low Temperature …, 2013 - pubs.aip.org
Magnetic properties of a Ce 3+ ion in two crystallographic phases of a nonsuperconducting
oxipnictide CeFeAsO were studied. Ce 3+-ion energy levels, g-factor values, temperature …

Effective nuclear charge approximation for free rare-earth ions

OV Gornostaeva, RY Babkin, KV Lamonova… - Spectroscopy …, 2017 - Taylor & Francis
ABSTRACT A semi-empirical method to describe the electron structure of free many-electron
rare-earth ions has been proposed. The method takes into account the spin–orbit interaction …

Low-dimensional magnetism of spin-½ chain systems of α-and β-TeVO4: A comparative study

V Gnezdilov, P Lemmens, D Wulferding… - Low Temperature …, 2012 - pubs.aip.org
We present a comparative study of the low-dimensional compounds α-and β-TeVO 4. Our
data clearly show that the change in the local coordination geometry of V 4+ ions between α …