Cathodic corrosion of metal electrodes—how to prevent it in electroorganic synthesis

T Wirtanen, T Prenzel, JP Tessonnier… - Chemical …, 2021 - ACS Publications
The critical aspects of the corrosion of metal electrodes in cathodic reductions are covered.
We discuss the involved mechanisms including alloying with alkali metals, cathodic etching …

Towards Sustainable Oxalic Acid from CO2 and Biomass

E Schuler, M Demetriou, NR Shiju… - ChemSusChem, 2021 - Wiley Online Library
To quickly and drastically reduce CO2 emissions and meet our ambitions of a circular future,
we need to develop carbon capture and storage (CCS) and carbon capture and utilization …

Electroreduction of CO2: Advances in the Continuous Production of Formic Acid and Formate

K Fernández-Caso, G Díaz-Sainz… - ACS Energy …, 2023 - ACS Publications
The study of the electrochemical CO2 reduction to obtain formate (HCOO–) or formic acid
(HCOOH) is receiving much attention as a promising technology. Since continuous–mode …

Ion Exchange Membranes in Electrochemical CO2 Reduction Processes

F Habibzadeh, P Mardle, N Zhao, HD Riley… - Electrochemical Energy …, 2023 - Springer
The low-temperature electrolysis of CO2 in membrane-based flow reactors is a promising
technology for converting captured CO2 into valuable chemicals and fuels. In recent years …

Elucidating cathodic corrosion mechanisms with operando electrochemical transmission electron microscopy

Y Yang, YT Shao, X Lu, Y Yang, HY Ko… - Journal of the …, 2022 - ACS Publications
Cathodic corrosion represents an enigmatic electrochemical process in which metallic
electrodes corrode under sufficiently reducing potentials. Although discovered by Fritz …

Enhanced electrochemical conversion of CO2 into formic acid using PbSO4/AtSn electrode: Catalyst synthesis and process optimization

M Arsalan, D Ewis, N Mahmud, MM Ba-Abbad… - Journal of …, 2023 - Elsevier
Electrochemical carbon dioxide (CO 2) reduction is among the most promising and effective
methods for producing valuable fuels while simultaneously addressing global warming …

Continuous electroconversion of CO2 into formate using 2 nm tin oxide nanoparticles

I Merino-Garcia, L Tinat, J Albo… - Applied Catalysis B …, 2021 - Elsevier
Abstract Tin oxide nanoparticles (SnO 2 NPs) as electrocatalyst for the production of formate
from CO 2 reduction reaction (CO 2 RR). We synthesize, characterize and evaluate high …

[HTML][HTML] Cathodic corrosion: 21st century insights into a 19th century phenomenon

TJP Hersbach, MTM Koper - Current Opinion in Electrochemistry, 2021 - Elsevier
Cathodic corrosion is an enigmatic electrochemical process that etches metallic electrodes
at potentials below 0 Volt versus the normal hydrogen electrode. Though this phenomenon …

Electrochemical synthesis of catalytic materials for energy catalysis

D Gao, H Li, P Wei, Y Wang, G Wang, X Bao - Chinese Journal of Catalysis, 2022 - Elsevier
Electrocatalysis is a process dealing with electrochemical reactions in the interconversion of
chemical energy and electrical energy. Precise synthesis of catalytically active …

[HTML][HTML] Continuous electroreduction of CO2 towards formate in gas-phase operation at high current densities with an anion exchange membrane

G Díaz-Sainz, M Alvarez-Guerra, A Irabien - Journal of CO2 Utilization, 2022 - Elsevier
The carbon dioxide (CO 2) electroreduction to formate is nowadays considered as a
promising approach to convert CO 2 into a value-added product and simultaneously, in the …