C–H functionalization has been emerging as a powerful method to establish carbon–carbon
and carbon–heteroatom bonds. Many efforts have been devoted to transition-metal …

As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

An unprecedented Pd‐catalyzed fluorinative bifunctionalization of aziridines and azetidines
was successfully developed via regioselective C− C and C− F bond cleavage of gem …

Phenols are important starting materials, intermediates, and functional elements of a very
broad range of chemicals and materials. They are large-volume products of benzene …

C–H bonds are ubiquitous in organic molecules. Homogenous gold-catalyzed direct
functionalization of unsaturated C–H bonds has emerged as a powerful method in our …

In contrast to transition metal-catalysed C–H functionalisation, highly efficient construction of
C–C and C–X (X= N, O, S, B, Si, etc.) bonds through metal-free catalytic C–H …

Lewis acidic boranes have been shown to be effective metal-free catalysts for highly
selective reactions of donor-acceptor diazo compounds to a range of substrates. The …

Tetraarylethylenes exhibit intriguing photophysical properties and sulfur atom frequently
play a vital role in organic photoelectric materials and biologically active compounds …

Asymmetric insertion of an arylvinylcarbenoid into the C–H bond for direct enantioselective
C (sp2)-H functionalization of aniline derivatives catalyzed by a rhodium (I)-diene complex …

Skipped dienes are not only present in fatty acid primary metabolites and natural products
but also serve as reactive intermediates in diverse chemical synthesis. Despite this, the …