Probing the binding and activation of small molecules by gas-phase transition metal clusters via IR spectroscopy
A Fielicke - Chemical Society Reviews, 2023 - pubs.rsc.org
Isolated transition metal clusters have been established as useful models for extended metal
surfaces or deposited metal particles, to improve the understanding of their surface …
surfaces or deposited metal particles, to improve the understanding of their surface …
CO oxidation as a prototypical reaction for heterogeneous processes
CO oxidation, although seemingly a simple chemical reaction, provides us with a panacea
that reveals the richness and beauty of heterogeneous catalysis. The Fritz Haber Institute is …
that reveals the richness and beauty of heterogeneous catalysis. The Fritz Haber Institute is …
Chemistry with methane: concepts rather than recipes
H Schwarz - Angewandte Chemie International Edition, 2011 - Wiley Online Library
Four seemingly simple transformations related to the chemistry of methane will be
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …
addressed from mechanistic and conceptual points of view: 1) metal‐mediated …
Atomically resolved chemical reactivity of small Fe clusters
J Berwanger, S Polesya, S Mankovsky, H Ebert… - Physical Review Letters, 2020 - APS
Small metal clusters have been investigated for decades due to their beneficial catalytic
activity. It was found that edges are most reactive and the number of catalytic events …
activity. It was found that edges are most reactive and the number of catalytic events …
Chemie mit Methan: Studieren geht über Probieren!
H Schwarz - Angewandte Chemie, 2011 - Wiley Online Library
Konzeptionelle Überlegungen zu und mechanistische Aspekte von vier scheinbar einfachen
chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in …
chemischen Umsetzungen, die in der Chemie von Methan von Bedeutung sind, werden in …
Platinum Group Metal Clusters: From Gas‐Phase Structures and Reactivities towards Model Catalysts
DJ Harding, A Fielicke - Chemistry–A European Journal, 2014 - Wiley Online Library
Transition‐metal clusters have long been proposed as model systems to study
heterogeneous catalysts. In this Concept article we show how advanced spectroscopic …
heterogeneous catalysts. In this Concept article we show how advanced spectroscopic …
[HTML][HTML] Cryo spectroscopy of N2 on cationic iron clusters
A Straßner, C Wiehn, MP Klein, DV Fries… - The Journal of …, 2021 - pubs.aip.org
Infrared photodissociation (IR-PD) spectra of iron cluster dinitrogen adsorbate complexes
[Fe n (N 2) m]+ for n= 8–20 reveal slightly redshifted IR active bands in the region of 2200 …
[Fe n (N 2) m]+ for n= 8–20 reveal slightly redshifted IR active bands in the region of 2200 …
N2 Activation by Neutral Ruthenium Clusters
The activation of nitrogen molecules when forming complexes with neutral Ru clusters in the
gas phase has been investigated by probing their N–N stretching frequencies using infrared …
gas phase has been investigated by probing their N–N stretching frequencies using infrared …
Die CO‐Oxidation als Modellreaktion für heterogene Prozesse
Die CO‐Oxidation, obwohl eine scheinbar einfache chemische Reaktion, dient als ein
Modell, welches die Vielfalt und Attraktivität der heterogenen Katalyse offenbart. Das Fritz …
Modell, welches die Vielfalt und Attraktivität der heterogenen Katalyse offenbart. Das Fritz …
Infrared spectroscopy of N 2 adsorption on size selected cobalt cluster cations in isolation
S Dillinger, J Mohrbach, J Hewer, M Gaffga… - Physical Chemistry …, 2015 - pubs.rsc.org
We report IR active N2 stretching frequencies in isolated and size selected cobalt cluster
nitrogen adsorbate complexes,[Con (N2) 1]+ as recorded by virtue of InfraRed Photon …
nitrogen adsorbate complexes,[Con (N2) 1]+ as recorded by virtue of InfraRed Photon …