Small molecule activation by well-defined compounds of heavy p-block elements

K Oberdorf, C Lichtenberg - Chemical Communications, 2023 - pubs.rsc.org
The creative design and exploration of new bonding motifs and molecular architectures in
main group chemistry have pushed the boundaries of reactivity in this field of research. In …

Homoleptic Transition Metal Carbonyl Cations: Synthetic Approaches, Characterization and Follow-Up Chemistry

M Sellin, I Krossing - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Carbon monoxide, CO, is one of the most important ligands in organometallic
chemistry. It is an excellent π-acceptor and a moderate σ-donor. Therefore, most of the …

Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation

S Zou, B Lou, K Yang, W Yuan, C Zhu, Y Zhu… - Nature …, 2021 - nature.com
Metal/oxide interface is of fundamental significance to heterogeneous catalysis because the
seemingly “inert” oxide support can modulate the morphology, atomic and electronic …

Self‐Accelerating Effect in a Covalent–Organic Framework with Imidazole Groups Boosts Electroreduction of CO2 to CO

MD Zhang, JR Huang, W Shi, PQ Liao… - Angewandte Chemie …, 2023 - Wiley Online Library
Solvent effect plays an important role in catalytic reaction, but there is little research and
attention on it in electrochemical CO2 reduction reaction (eCO2RR). Herein, we report a …

Overcoming immiscibility toward bimetallic catalyst library

C Yang, BH Ko, S Hwang, Z Liu, Y Yao, W Luc… - Science …, 2020 - science.org
Bimetallics are emerging as important materials that often exhibit distinct chemical
properties from monometallics. However, there is limited access to homogeneously alloyed …

Metal–CO bonding in mononuclear transition metal carbonyl complexes

G Frenking, I Fernández, N Holzmann, S Pan… - Jacs Au, 2021 - ACS Publications
DFT calculations have been carried out for coordinatively saturated neutral and charged
carbonyl complexes [M (CO) n] q where M is a metal atom of groups 2–10. The model …

General strategy for evaluating the d-band center shift and ethanol oxidation reaction pathway towards Pt-based electrocatalysts

JH Zheng, G Li, JM Zhang, N Cheng, LF Ji… - Science China …, 2023 - Springer
The catalytic performance of Pt-based catalysts depends sensitively on their d-band centers.
Nevertheless, there are still huge challenges to evaluate their d-band centers from …

Catalytic Au (I)/Au (III) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles

J Rodriguez, A Zeineddine, EDS Carrizo, K Miqueu… - Chemical …, 2019 - pubs.rsc.org
The ability of the hemilabile (P, N) MeDalphos ligand to trigger oxidative addition of
iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett …

PLA thermoformed trays incorporated with cinnamaldehyde and carvacrol as active biodegradable bakery packaging

H Gonon, A Srisa, K Promhuad, V Chonhenchob… - Food Packaging and …, 2023 - Elsevier
Abstract Poly (lactic acid)(PLA) with enhanced antimicrobial functions can be used as
sustainable food packaging to control microbial growth and reduce waste. PLA trays …

Fischer–Tropsch: product selectivity–the fingerprint of synthetic fuels

WD Shafer, MK Gnanamani, UM Graham, J Yang… - Catalysts, 2019 - mdpi.com
The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a
wide range (C1–C70+) of hydrocarbons, primarily straight-chained paraffins. Additional …