Small molecule activation by well-defined compounds of heavy p-block elements
K Oberdorf, C Lichtenberg - Chemical Communications, 2023 - pubs.rsc.org
The creative design and exploration of new bonding motifs and molecular architectures in
main group chemistry have pushed the boundaries of reactivity in this field of research. In …
main group chemistry have pushed the boundaries of reactivity in this field of research. In …
Homoleptic Transition Metal Carbonyl Cations: Synthetic Approaches, Characterization and Follow-Up Chemistry
M Sellin, I Krossing - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Carbon monoxide, CO, is one of the most important ligands in organometallic
chemistry. It is an excellent π-acceptor and a moderate σ-donor. Therefore, most of the …
chemistry. It is an excellent π-acceptor and a moderate σ-donor. Therefore, most of the …
Grafting nanometer metal/oxide interface towards enhanced low-temperature acetylene semi-hydrogenation
Metal/oxide interface is of fundamental significance to heterogeneous catalysis because the
seemingly “inert” oxide support can modulate the morphology, atomic and electronic …
seemingly “inert” oxide support can modulate the morphology, atomic and electronic …
Self‐Accelerating Effect in a Covalent–Organic Framework with Imidazole Groups Boosts Electroreduction of CO2 to CO
MD Zhang, JR Huang, W Shi, PQ Liao… - Angewandte Chemie …, 2023 - Wiley Online Library
Solvent effect plays an important role in catalytic reaction, but there is little research and
attention on it in electrochemical CO2 reduction reaction (eCO2RR). Herein, we report a …
attention on it in electrochemical CO2 reduction reaction (eCO2RR). Herein, we report a …
Overcoming immiscibility toward bimetallic catalyst library
Bimetallics are emerging as important materials that often exhibit distinct chemical
properties from monometallics. However, there is limited access to homogeneously alloyed …
properties from monometallics. However, there is limited access to homogeneously alloyed …
Metal–CO bonding in mononuclear transition metal carbonyl complexes
G Frenking, I Fernández, N Holzmann, S Pan… - Jacs Au, 2021 - ACS Publications
DFT calculations have been carried out for coordinatively saturated neutral and charged
carbonyl complexes [M (CO) n] q where M is a metal atom of groups 2–10. The model …
carbonyl complexes [M (CO) n] q where M is a metal atom of groups 2–10. The model …
General strategy for evaluating the d-band center shift and ethanol oxidation reaction pathway towards Pt-based electrocatalysts
JH Zheng, G Li, JM Zhang, N Cheng, LF Ji… - Science China …, 2023 - Springer
The catalytic performance of Pt-based catalysts depends sensitively on their d-band centers.
Nevertheless, there are still huge challenges to evaluate their d-band centers from …
Nevertheless, there are still huge challenges to evaluate their d-band centers from …
Catalytic Au (I)/Au (III) arylation with the hemilabile MeDalphos ligand: unusual selectivity for electron-rich iodoarenes and efficient application to indoles
J Rodriguez, A Zeineddine, EDS Carrizo, K Miqueu… - Chemical …, 2019 - pubs.rsc.org
The ability of the hemilabile (P, N) MeDalphos ligand to trigger oxidative addition of
iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett …
iodoarenes to gold has been thoroughly studied. Competition experiments and Hammett …
PLA thermoformed trays incorporated with cinnamaldehyde and carvacrol as active biodegradable bakery packaging
Abstract Poly (lactic acid)(PLA) with enhanced antimicrobial functions can be used as
sustainable food packaging to control microbial growth and reduce waste. PLA trays …
sustainable food packaging to control microbial growth and reduce waste. PLA trays …
Fischer–Tropsch: product selectivity–the fingerprint of synthetic fuels
The bulk of the products that were synthesized from Fischer–Tropsch synthesis (FTS) is a
wide range (C1–C70+) of hydrocarbons, primarily straight-chained paraffins. Additional …
wide range (C1–C70+) of hydrocarbons, primarily straight-chained paraffins. Additional …