Selective electrochemical oxidation of benzylic C–H to benzylic alcohols with the aid of imidazolium radical mediators

F Peng, J Xiang, H Qin, B Chen, R Duan… - Journal of the …, 2023 - ACS Publications
Selective oxidation of benzylic C–H to benzylic alcohols is a well-known challenge in the
chemical community since benzylic C–H is more prone to be overoxidized to benzylic …

Photo- and Solvent-Mediated Production of the Highly Reactive N-Oxyl Radical and Its Efficient Catalytic Oxidation of Hydrocarbons at Ambient Temperature

Z Zhu, Q Zhang, D Xie, H Liu, H Wang… - ACS Sustainable …, 2022 - ACS Publications
Selective oxidation of hydrocarbons with molecular oxygen at ambient temperature is full of
challenge, and efficient activation of the inert C–H bond under mild conditions is the …

Two copper-containing polyoxometalate-based metal–organic complexes as heterogeneous catalysts for the C–H bond oxidation of benzylic compounds and olefin …

Y Zheng, Q Shen, Z Li, X Jing, C Duan - Inorganic Chemistry, 2022 - ACS Publications
Using a one-pot assembly method, two novel copper-containing Keggin-type
polyoxometalates (POMs)-based metal–organic complexes, that is,[CuII2 (pbba) 2NO3 …

Tuning redox activity in metal–organic frameworks: From structure to application

SAA Razavi, W Chen, HC Zhou, A Morsali - Coordination Chemistry …, 2024 - Elsevier
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …

Anthraquinone-Based Metal–Organic Frameworks as a Bifunctional Photocatalyst for C–H Activation

L Zhao, W Cai, G Ji, J Wei, Z Du, C He… - Inorganic …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have gained attention as multifunctional catalytic
platforms, allowing us to gain important insights into synergistically activating both C–H …

Highly efficient multi-site synergistic catalysis of a polyoxovanadate-based metal–organic framework for benzylic C–H bond oxidation

TY Dang, RH Li, HR Tian, W Guan, Y Lu… - Journal of Materials …, 2022 - pubs.rsc.org
The selective oxidation of C–H bonds of benzylic compounds to synthesize high-value-
added ketones remains a challenge under mild conditions, and the ambiguity of its oxidation …

Iron/photoredox dual catalysis for acyl nitrene-based C–O bond formation towards phthalides

Z Zhang, Y Deng, M Hou, X Lai, M Guan… - Chemical …, 2022 - pubs.rsc.org
This paper describes iron/photoredox dual-catalyzed acyl nitrene formation and the use of
acyl nitrene in constructing various C–O bonds towards phthalides. The developed reaction …

Vanadium(VIV)–Porphyrin-Based Metal–Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)–H Bonds

Y Wang, L Zhao, G Ji, C He, S Liu… - ACS Applied Materials & …, 2022 - ACS Publications
Activation and selective functionalization of inert C (sp3)–H bonds remain one of the most
challenging tasks in current synthetic chemistry. Herein, by decorating vanadium (VIV) …

Robust Bio-derived Polyoxometalate Hybrid for Selective Aerobic Oxidation of Benzylic C(sp3)–H Bonds

J Song, M Hua, X Huang, J Ma, C Xie, B Han - ACS Catalysis, 2023 - ACS Publications
Utilization of natural resources to construct functional catalytic materials for challenging
organic reactions is of great importance in the chemical community, which has achieved …

Constructing Functional Radiation-Resistant Thorium Clusters for Catalytic Redox Reactions

Q Niu, TY Yu, JW Shi, Q Huang, LZ Dong… - Journal of the …, 2024 - ACS Publications
When catalytic reactions are interfered with by radiation sources, thorium clusters are
promising as potential catalysts due to their superior radiation resistance. However, there is …