Selective electrochemical oxidation of benzylic C–H to benzylic alcohols with the aid of imidazolium radical mediators
F Peng, J Xiang, H Qin, B Chen, R Duan… - Journal of the …, 2023 - ACS Publications
Selective oxidation of benzylic C–H to benzylic alcohols is a well-known challenge in the
chemical community since benzylic C–H is more prone to be overoxidized to benzylic …
chemical community since benzylic C–H is more prone to be overoxidized to benzylic …
Photo- and Solvent-Mediated Production of the Highly Reactive N-Oxyl Radical and Its Efficient Catalytic Oxidation of Hydrocarbons at Ambient Temperature
Z Zhu, Q Zhang, D Xie, H Liu, H Wang… - ACS Sustainable …, 2022 - ACS Publications
Selective oxidation of hydrocarbons with molecular oxygen at ambient temperature is full of
challenge, and efficient activation of the inert C–H bond under mild conditions is the …
challenge, and efficient activation of the inert C–H bond under mild conditions is the …
Two copper-containing polyoxometalate-based metal–organic complexes as heterogeneous catalysts for the C–H bond oxidation of benzylic compounds and olefin …
Y Zheng, Q Shen, Z Li, X Jing, C Duan - Inorganic Chemistry, 2022 - ACS Publications
Using a one-pot assembly method, two novel copper-containing Keggin-type
polyoxometalates (POMs)-based metal–organic complexes, that is,[CuII2 (pbba) 2NO3 …
polyoxometalates (POMs)-based metal–organic complexes, that is,[CuII2 (pbba) 2NO3 …
Tuning redox activity in metal–organic frameworks: From structure to application
Among the various characteristics of metal–organic frameworks (MOFs), redox activity, the
ability to store or release electrons is a vital property for functional MOFs in applications like …
ability to store or release electrons is a vital property for functional MOFs in applications like …
Anthraquinone-Based Metal–Organic Frameworks as a Bifunctional Photocatalyst for C–H Activation
L Zhao, W Cai, G Ji, J Wei, Z Du, C He… - Inorganic …, 2022 - ACS Publications
Metal–organic frameworks (MOFs) have gained attention as multifunctional catalytic
platforms, allowing us to gain important insights into synergistically activating both C–H …
platforms, allowing us to gain important insights into synergistically activating both C–H …
Highly efficient multi-site synergistic catalysis of a polyoxovanadate-based metal–organic framework for benzylic C–H bond oxidation
TY Dang, RH Li, HR Tian, W Guan, Y Lu… - Journal of Materials …, 2022 - pubs.rsc.org
The selective oxidation of C–H bonds of benzylic compounds to synthesize high-value-
added ketones remains a challenge under mild conditions, and the ambiguity of its oxidation …
added ketones remains a challenge under mild conditions, and the ambiguity of its oxidation …
Iron/photoredox dual catalysis for acyl nitrene-based C–O bond formation towards phthalides
Z Zhang, Y Deng, M Hou, X Lai, M Guan… - Chemical …, 2022 - pubs.rsc.org
This paper describes iron/photoredox dual-catalyzed acyl nitrene formation and the use of
acyl nitrene in constructing various C–O bonds towards phthalides. The developed reaction …
acyl nitrene in constructing various C–O bonds towards phthalides. The developed reaction …
Vanadium(VIV)–Porphyrin-Based Metal–Organic Frameworks for Synergistic Bimetallic Activation of Inert C(sp3)–H Bonds
Y Wang, L Zhao, G Ji, C He, S Liu… - ACS Applied Materials & …, 2022 - ACS Publications
Activation and selective functionalization of inert C (sp3)–H bonds remain one of the most
challenging tasks in current synthetic chemistry. Herein, by decorating vanadium (VIV) …
challenging tasks in current synthetic chemistry. Herein, by decorating vanadium (VIV) …
Robust Bio-derived Polyoxometalate Hybrid for Selective Aerobic Oxidation of Benzylic C(sp3)–H Bonds
Utilization of natural resources to construct functional catalytic materials for challenging
organic reactions is of great importance in the chemical community, which has achieved …
organic reactions is of great importance in the chemical community, which has achieved …
Constructing Functional Radiation-Resistant Thorium Clusters for Catalytic Redox Reactions
Q Niu, TY Yu, JW Shi, Q Huang, LZ Dong… - Journal of the …, 2024 - ACS Publications
When catalytic reactions are interfered with by radiation sources, thorium clusters are
promising as potential catalysts due to their superior radiation resistance. However, there is …
promising as potential catalysts due to their superior radiation resistance. However, there is …