Surface effect of the MgCl2 support in Ziegler–Natta catalyst for ethylene polymerization: A computational study

K Xie, S Xu, W Hao, J Wang, A Huang, Y Zhang - Applied Surface Science, 2022 - Elsevier
Abstract Ziegler–Natta (Z–N) catalyst is a remarkable catalyst for olefin polymerization in the
petrochemical industry. However, the role of each component remains unclear because of …

Exploring cocatalyst type effect on the Ziegler–Natta catalyzed ethylene polymerizations: Experimental and DFT studies

M Masoori, M Nekoomanesh, S Posada-Pérez… - Journal of Polymer …, 2022 - Springer
Due to the important role of cocatalyst in the polymerization process employing industrially
favored Ziegler–Natta catalysts, its effect on kinetic behavior, catalyst activity, and polymer …

A systematic study on the effect of co-catalysts composition on the performance of Ziegler-Natta catalyst in ethylene/1-butene co-polymerizations

M Masoori, M Nekoomanesh, S Posada-Pérez… - Polymer, 2022 - Elsevier
Abstract Effect of the type and composition of conventional co-catalysts on the catalytic
performance of Ziegler-Natta catalysts has been investigated by means of a combined …

Demystifying the two-sided role of inorganic halides in the structure and performance of Ziegler–Natta catalysts

MH Jandaghian, Y Maddah, S Hosseini… - … Systems Design & …, 2022 - pubs.rsc.org
In this paper, the results of adding SiCl4 (as a model inorganic halide) to the formulation of
an industrially well-known Ziegler–Natta catalyst (ZNC) have been investigated to shed light …

Polyolefin Catalyst Research: A Product‐Driven Industrial Perspective

M Atiqullah, HS Al‐Asiri - The Chemical Record, 2022 - Wiley Online Library
This account narrates polyolefin catalyst research at the Research Institute Interdisciplinary
Research Center for Refining & Advanced Chemicals (IRCRAC). We particularly address …

Chemical dealcoholation of MgCl2·EtOH adduct by Al compounds and its effect on the performance of Ziegler–Natta catalysts

R Bazvand, N Bahri‐Laleh, H Abedini… - Applied …, 2024 - Wiley Online Library
MgCl2· nEtOH adducts play a major role in the industrial production of polyethylenes. Their
chemical dealcoholation, usually accomplished during the catalyst synthesis step, has had a …

Hydrophilic Core-Sheath fibers of polyvinyl alcohol/polyethylene composites through in situ ethylene polymerization

H Bhajiwala, IK HR, RB Patankar, B Desai… - European Polymer …, 2022 - Elsevier
Core-sheath fibers of polyvinyl alcohol/polyethylene composites are synthesized by
ethylene polymerization with titanium tetrachloride incorporated PVA nanofiber (NF) as …

Orbital-scale understanding of the surface effect of the MgCl2 in the Ziegler–Natta catalyst for ethylene polymerization: A computational study

K Xie, A Huang, P Zhang, X Wang, Y Zhang… - Chemical Engineering …, 2024 - Elsevier
Ziegler-Natta catalyst is a widely used olefin polymerization catalyst in petrochemical
industries. However, the role of each catalyst component is not clear due to the complexity of …

Insight of polypropylene synthesis with high performance multidentate internal donor catalyst system

PM Trivedi, CP Gocher… - Journal of applied …, 2023 - Wiley Online Library
Propylene polymerization using magnesium dichloride (MgCl2) supported Ziegler–Natta (Z–
N) system is a robust and preferred catalytic process for producing polypropylene (PP) …

Phenyl-bridged bis-salicylaldiminato binuclear titanium complexes for ethylene (co) polymerization

M Xue, Y Luo, S Ren, T Li, Q You, G Xie - Journal of Polymer Research, 2023 - Springer
P-Phenyl-bridged bis-salicylaldiminato binuclear titanium complexes Ti 2 L 1, Ti 2 L 2 and
the corresponding momonuclear counterpart TiL 4 were synthesized and characterized by …