Straightforward procedures for the generation of rhodium (I) κCl–chlorocarbon complexes of
the form [Rh (PONOP-t Bu)(κ Cl–ClR)][BArF4][R= CH2Cl, A; Ph, 1; Cy, 2; t Bu, 3; PONOP-t …

The UV absorption spectrum and kinetics of CH2I and CH2IO2 radicals have been studied
in the gasphase at 295 K using a pulse radiolysis UV absorption spectroscopic technique …

Employing a high-resolution (velocity resolution Δ ν∕ ν< 1.5%⁠) time-sliced ion velocity
imaging apparatus, we have examined the photodissociation of CH 2 BrCl in the photon …

Experiments on the plasma-assisted decomposition of dilute concentrations of methylene
chloride in atmospheric-pressure N2 and dry air streams by electron beam and pulsed …

The UV absorption spectra of the bromomethyl (CH2Br) and bromomethylperoxy (CH2BrO2)
radicals have been determined using the flash photolysis technique. CH2Br exhibits the …

Canonical flexible transition state theory is applied to the recombination of CX3 radicals (X=
H, F, Cl) using a simple model for the potential-energy surface. The limiting high-pressure …

Thermal decomposition of 1, 2-dichloroethane (1, 2-DCE) has been studied in the
temperature range of 1050− 1175 K behind reflected shock waves in a single pulse shock …

First high-resolution infrared spectra are presented for jet-cooled CH 2 Cl 35 and CH 2 Cl 37
radicals in the symmetric (ν 1) CH 2 stretching mode. A detailed spectral assignment yields …

This work presents a comprehensive kinetic modeling study of the pyrolysis and oxidation of
chloromethane. Theoretical calculations were performed for the decomposition reaction …

We investigate the Ã-band photodissociation of CHBrCl2 at 215, 225, 235, 245, 255, and
265 nm. Following C–Br bond cleavage, resonance enhanced multiphoton ionization and …