Because sunlight is the most abundant energy source on earth, it has huge potential for
practical applications ranging from sustainable energy supply to light driven chemistry. From …

Supramolecular radical chemistry has been emerging as a cutting-edge interdisciplinary
field of traditional supramolecular chemistry and radical chemistry in recent years. The …

Supramolecular containers featuring both high catalytic activity and high enantioselectivity
represent a design challenge of practical importance. Herein, it is demonstrated that a chiral …

The Kemp elimination (reaction of benzisoxazole with base to give 2-cyanophenolate) is
catalyzed in the cavity of a cubic M8L12 coordination cage because of a combination of (i) …

Modifying the reactivity of substrates by encapsulation is a fundamental principle of capsule
catalysis. Here we show an alternative strategy, wherein catalytic activation of otherwise …

A highly luminescent Zn4L6 tetrahedron is reported with 3.8 nm perylene bisimide edges
and hexadentate ZnII–imine chelate vertices. Replacing FeII and monoamines commonly …

The use of small molecules with defined cavities that catalyze unique chemical
transformations to emulate enzyme sites have resulted in sustainable catalytic …

Developing new photocatalysts for reduction of nitroarenes to anilines under mild conditions
is very significant. Herein, a new polyoxometalate-based metal–organic framework …

The utilization of photocatalytic techniques for achieving light‐to‐fuel conversion is a
promising way to ease the shortage of energy and degradation of the ecological …

Supramolecular macrocycles with intrinsic cavities have been widely explored as containers
to fabricate versatile functional materials via specific host–guest recognitions. However …