Organoelement chemistry: Promising growth areas and challenges

GA Abakumov, AV Piskunov… - Russian Chemical …, 2018 - iopscience.iop.org
The chemistry of organoelement compounds is now one of the most rapidly developing
fields of research, regarding both fundamental science and solution of applied problems …

General Concepts and Recent Advances in the Electrochemical Transformation of Chloro‐and Hydrosilanes

AD Beck, S Haufe, SR Waldvogel - ChemElectroChem, 2023 - Wiley Online Library
Organosilanes play an important role in organic synthesis as well as in a variety of further
areas, ranging from life science to transportation. Especially, the electrochemical access has …

Derivatives of penta-, hexa-, and hepta-coordinated tin with Schiff bases and 1, 10-phenanthroline: structure, redox and optoelectronic properties

IV Krylova, LD Labutskaya, MO Markova… - New Journal of …, 2023 - pubs.rsc.org
Tin coordination derivatives are notable for the availability, safety in use and high stability.
This advantage, together with their useful properties, determines the prospects for their use …

Halogen-free GeO 2 conversion: electrochemical reduction vs. complexation in (DTBC) 2 Ge [Py (CN) n](n= 0… 2) complexes

EN Nikolaevskaya, EA Saverina, AA Starikova… - Dalton …, 2018 - pubs.rsc.org
3, 5-di-tert-Butylcatecholate (DTBC) germanium complexes (DTBC) 2Ge [Py (CN) n] 2 (n=
0… 2) have been synthesized from GeO2, 3, 5-di-tert-butylcatechol and cyano-substituted …

Supramolecular D⋯ A-layered structures based on germanium complexes with 2, 3-dihydroxynaphthalene and N, N′-bidentate ligands

PG Shangin, IV Krylova, AV Lalov, AY Kozmenkova… - RSC …, 2021 - pubs.rsc.org
The concept of using redox-active ligands, which has become extremely widespread in
organometallic chemistry, is often considered from 'their effect on the metal center properties' …

Перспективные точки роста и вызовы элементоорганической химии

ГА Абакумов, АВ Пискунов, ВК Черкасов… - Успехи химии, 2018 - mathnet.ru
Химия элементоорганических соединений в настоящее время—одна из самых
динамично развивающихся научных областей как в плане фундаментальных …

Germanium‐centered Ion Radicals

MP Egorov, VV Jouikov… - Organogermanium …, 2023 - Wiley Online Library
Primary products of single‐electron transfer to/from organogermanium compounds (anion
radicals and cation radicals issued from reduction and oxidation, respectively) and their …

The Redox Properties of Germylenes Stabilized by N‐Donor Ligands

AY Kozmenkova, VA Timofeeva… - European Journal of …, 2021 - Wiley Online Library
Germylenes, organic compounds of divalent germanium, are often considered as promising
catalytic systems efficient in reactions of oxidative addition and reductive elimination …

Nucleophilic displacement versus electron transfer in the reactions of alkyl chlorosilanes with electrogenerated aromatic anion radicals

S Soualmi, M Dieng, A Ourari, D Gningue-Sall… - Electrochimica …, 2015 - Elsevier
Anion radicals of a series of aromatic compounds (C 6 H 5 CN, C 6 H 5 COOEt, anthracene,
9, 10-dimethyl-, 9, 10-diphenyl-and 9-phenylanthracene, pyrene and naphthalene) react …

Trimethylacetate-bridged mixed-valence binuclear vanadium (IV, V) complexes with a {(VO) 2 (μ-O)} 3+ core

ES Bazhina, GG Aleksandrov, MA Kiskin, OM Nikitin… - Polyhedron, 2020 - Elsevier
The reaction of an oxidovanadium (IV) salt with an N-donor ligand (2, 2′-bipyridine (bpy) or
4, 4′-di-tert-butyl-2, 2′-bipyridine (dtb-bpy)) and M (piv)(M= Li, K, NBu 4; piv=(CH 3) 3 …