Magnetic relaxation in single-ion magnets formed by less-studied lanthanide ions Ce (III), Nd (III), Gd (III), Ho (III), Tm (II/III) and Yb (III)

A Borah, R Murugavel - Coordination Chemistry Reviews, 2022 - Elsevier
Recent growth in the area of single-molecule magnets (SMMs) in general, and single-ion
magnets (SIMs) in particular, is due to the potential applications of this class of compounds …

Lanthanide Single‐molecule Magnets: Synthetic Strategy, Structures, Properties and Recent Advances

J Wang, CY Sun, Q Zheng, DQ Wang… - Chemistry–An Asian …, 2023 - Wiley Online Library
Single‐molecule magnets (SMMs) show wide potential applications in the field of ultrahigh‐
density storage materials, quantum computing, spintronics, and so on. Lanthanide (Ln) …

An Effective Strategy of Introducing Chirality to Achieve Multifunctionality in Rare‐Earth Double Perovskite Ferroelectrics

ZB Hu, CF Wang, TT Sha, C Shi, L Ye, HY Ye… - Small …, 2022 - Wiley Online Library
The hybrid rare‐earth double perovskite (HREDP) system provides great convenience for
the construction of multifunctional materials. However, suffering from the high symmetry of …

Importance of an Axial LnIII–F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues

E Regincós Martí, AB Canaj, T Sharma… - Inorganic …, 2022 - ACS Publications
The recently reported compound [DyIIILF](CF3SO3) 2· H2O (L= 1, 4, 7, 10-tetrakis (2-
pyridylmethyl)-1, 4, 7, 10-tetraaza-cyclododecane) displays a strong axial magnetic …

Insights into the Spin Dynamics of Mononuclear Cerium (III) Single-Molecule Magnets

FA Mautner, F Bierbaumer, RC Fischer… - Inorganic …, 2022 - ACS Publications
Four novel CeIII mononuclear complexes of formulas [Ce (ntfa) 3 (MeOH) 2](1),[Ce (ntfa) 3
(5, 5′-Me2bipy)](2),[Ce (ntfa) 3 (terpy)](3), and [Ce (ntfa) 3 (bipy) 2](4), where ntfa= 4, 4, 4 …

Field-induced SIM behaviour in early lanthanide (iii) organophosphates containing 18-crown-6

A Borah, S Dey, SK Gupta, G Rajaraman… - Dalton …, 2023 - pubs.rsc.org
Single-ion magnets (SIMs) have attracted wide attention in recent years. Despite
tremendous progress in late lanthanide SIMs, reports on early lanthanides exhibiting SIM …

Field-induced magnetic relaxation in heteropolynuclear Ln III/Zn II metal organic frameworks: cerium and dysprosium cases

A López, C Cruz, V Paredes-García, N Veiga… - New Journal of …, 2023 - pubs.rsc.org
This study focuses on investigating the magnetic properties of the CeIII-based metal–organic
framework [Ce2Zn3 (oda) 6 (H2O) 6]· 12H2O (1), along with the hexagonal and cubic …

Slow magnetic relaxation of mononuclear complexes based on uncommon Kramers lanthanide ions Ce III, Sm III and Yb III

JD Leng, QY Hua, WT Liu, ZX Tao, NW Tan… - Dalton …, 2022 - pubs.rsc.org
Based on the uncommon Kramers ions CeIII, SmIII and YbIII, complexes [Ce (dppbO2)
2Cl3](1, dppbO2= 1, 2-bis (diphenylphosphino) benzene dioxide),[Sm (dppbO2) 2Cl3](2) …

Single-Ion Anisotropy and Intramolecular Interactions in CeIII and NdIII Dimers

J Mayans, L Tesi, M Briganti, ME Boulon… - Inorganic …, 2021 - ACS Publications
This article reports the syntheses, characterization, structural description, together with
magnetic and spectroscopic properties of two isostructural molecular magnets based on the …

First-principles investigations of magnetic anisotropy and spin-crossover behavior of Fe (III)–TBP complexes

R Khurana, S Gupta, ME Ali - The Journal of Physical Chemistry A, 2021 - ACS Publications
With the ongoing effort to obtain mononuclear 3d-transition-metal complexes that manifest
slow relaxation of magnetization and, hence, can behave as single-molecule magnets …