Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and
sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due …

Solid‐state electrolytes have attracted considerable attention in new energy‐related devices
due to their high safety and broad application platform. Polyoxometalates (POMs) are a kind …

Only rarely have polyoxometalates been found to form core–shell nanoclusters. Here, we
succeeded in isolating a series of rare giant and all‐inorganic core–shell cobalt …

This review is intended to provide an up-to-date and comprehensive description of recent
advances since the mid-2010s in the elaboration and the involvement of polyoxometalates …

Abstract A protein‐sized (ca. 4.2× 4.2× 3.6 nm3) non‐biologically derived molecule
{Nb288O768 (OH) 48 (CO3) 12}(Nb288) containing up to 288 niobium atoms has been …

Hydrogen energy derived from water splitting is the cleanest renewable energy source, but it
is also very challenging to achieve because the hydrogen evolution reaction (HER) requires …

A building blocks strategy is an effective approach for constructing the large molecular
systems. Herein, we demonstrate that high‐resolution electro‐spray ionization mass …

Self‐assembly of metavanadate and organosilver (I) salts leads to a novel dodecahedrane‐
like [Ag30 (tBuS) 20] 10+ silver (I) thiolate nanocage that tightly wraps an unusual C2h …

The first series of niobium–tungsten–lanthanide (Nb‐W‐Ln) heterometallic
polyoxometalates {Ln12W12O36 (H2O) 24 (Nb6O19) 12}(Ln= Y, La, Sm, Eu, Yb) have been …

Amorphous molybdenum oxysulfide MoOS 2 obtained by acidification of aqueous MoO 2 S
2 2− solutions was structurally characterized and tested as a catalyst for hydrogen evolution …