Theoretical description of the spectroscopic properties of rare earth ions in crystals

L Smentek - Physics Reports, 1998 - Elsevier
In this article the present state of knowledge of the theory of one-and two-photon processes
observed in rare earth ions in crystals is presented. The conclusions are based on the …

Judd‐Ofelt Theory — The Golden (and the Only One) Theoretical Tool of f‐Electron Spectroscopy

L Smentek - … Methods in Lanthanide and Actinide Chemistry, 2015 - Wiley Online Library
The year 2012 marked the golden anniversary of the Judd‐Ofelt (J‐O) theory as a tool used
widely for the theoretical description of the spectroscopic properties of the lanthanide …

Judd—Ofelt theory: past, present and future

L Smentek - Molecular Physics, 2003 - Taylor & Francis
The original Judd-Ofelt theory is briefly presented in the terms of effective operators defined
in the traditional form that has been used for many years for the interpretation of the f spectra …

Theoretical description of 0 0 and 0 1 transitions in the Eu3+ ion in hosts with C2v symmetry

L Smentek, B ANDES HESS - Molecular Physics, 1997 - Taylor & Francis
The results of numerical analysis performed for the electric dipole transitions observed in
Eu3+ in the host with C symmetry are presented. The discussion is focused on the one …

Third order abinitio calculations of the ff transition amplitudes for ions across the lanthanide series

L Smentek‐Mielczarek, B Andes Hess Jr - The Journal of chemical …, 1988 - pubs.aip.org
The behavior of various contributions to the f↔ f transition amplitude defined up to the third
order in perturbation theory is analyzed. Main attention is paid to the third‐order …

Judd–Ofelt theory in a new light on its (almost) 40th anniversary

L Smentek, BG Wybourne, BA Hess Jr - Journal of alloys and compounds, 2001 - Elsevier
The standard Judd–Ofelt theory of one photon electric dipole transitions in fN systems is
discussed in the language of the one particle parametrization scheme. An overview of …

f↔ f electric dipole transitions; old problems in a new light

L Smentek, A Kȩdziorski - Journal of alloys and compounds, 2009 - Elsevier
Very well known difficulties of the theoretical description of the f↔ f electric dipole transitions
of lanthanides are addressed in the old language of the standard Judd–Ofelt (J–O) theory …

Third-order electron-correlation and crystal-field contributions to the amplitudes of two-photon absorption in systems

L Smentek-Mielczarek, BA Hess Jr - Physical Review B, 1987 - APS
A method of analysis of the influence of electron correlation and crystal field on single-beam
two-photon absorption amplitudes is presented. The approach is based on the double …

Third‐order abinitio calculations of the intensity parameters for the Pr+3 ion in LaAlO3, NdAlO3, and LaCl3 hosts

L Smentek‐Mielczarek, BA Hess Jr - The Journal of chemical physics, 1987 - pubs.aip.org
The values of intensity parameters for the Pr+ 3 ion in LaAlO3, NdAlO3, and LaCl3 hosts
evaluated with complete ab initio calculations based on the third‐order f↔ f transition theory …

Parametric analysis of ff transition intensities in trigonal Na3 [Nd (oxydiacetate) 3]· 2NaClO4· 6H2O

PS May, CK Jayasankar, FS Richardson - Chemical physics, 1989 - Elsevier
Optical intensity data available from axial and polarized orthoaxial absorption
measurements on single crystals of trigonal Na 3 [Nd (oxydiacetate) 3]· 2NaClO 4· 6H 2 O …