History repeats itself again: Will the mistakes of the past for ILs be repeated for DESs? From being considered ionic liquids to becoming their alternative: The …

J Afonso, A Mezzetta, IM Marrucho, L Guazzelli - Green Chemistry, 2023 - pubs.rsc.org
The establishment of the place of Deep Eutectic Solvents (DESs) as a new class of green
solvents was essentially grounded on naïve comparisons with Ionic Liquids (ILs), since both …

Ionic liquids and deep eutectics as a transformative platform for the synthesis of nanomaterials

OS Hammond, AV Mudring - Chemical Communications, 2022 - pubs.rsc.org
Ionic liquids (ILs) are becoming a revolutionary synthesis medium for inorganic
nanomaterials, permitting more efficient, safer and environmentally benign preparation of …

Computer simulations of deep eutectic solvents: Challenges, solutions, and perspectives

D Tolmachev, N Lukasheva, R Ramazanov… - International journal of …, 2022 - mdpi.com
Deep eutectic solvents (DESs) are one of the most rapidly evolving types of solvents,
appearing in a broad range of applications, such as nanotechnology, electrochemistry …

Combining acid-based deep eutectic solvents and microwave irradiation for improved chestnut shell waste valorization

J González-Rivera, A Mero, E Husanu, A Mezzetta… - Green …, 2021 - pubs.rsc.org
A microwave (MW)/deep eutectic solvent (DES)-assisted (MWDA) extraction process for
obtaining value-added compounds from chestnut shell waste (CSW) is presented. DESs …

Extraction of flavonoids from Glycyrrhiza residues using deep eutectic solvents and its molecular mechanism

Q Yu, F Wang, Y Jian, VM Chernyshev, Y Zhang… - Journal of Molecular …, 2022 - Elsevier
The re-extraction of bioactive compounds from Chinese herb residues is significant for the
maximum utilization of biomass resources. However, conventional alcoholic and aqueous …

In competition for water: hydrated choline chloride: urea vs choline acetate: urea deep eutectic solvents

ME Di Pietro, M Tortora, C Bottari… - ACS Sustainable …, 2021 - ACS Publications
Unlike the archetypal deep eutectic solvent (DES) choline chloride: urea (ChCl: U),
fundamental knowledge of the intermolecular network in choline acetate (ChOAc) DESs and …

Transitioning from ionic liquids to deep eutectic solvents

H Zhang, JM Vicent-Luna, S Tao, S Calero… - ACS Sustainable …, 2022 - ACS Publications
Ionic liquids (ILs) and deep eutectic solvents (DESs) have been lately the solvents of choice
in a number of processes because they offer a valid alternative to conventional solvents …

Promising technological and industrial applications of deep eutectic systems

A Mannu, M Blangetti, S Baldino, C Prandi - Materials, 2021 - mdpi.com
Deep Eutectic Systems (DESs) are obtained by combining Hydrogen Bond Acceptors
(HBAs) and Hydrogen Bond Donors (HBDs) in specific molar ratios. Since their first …

Trace Water Changes Metal Ion Speciation in Deep Eutectic Solvents: Ce3+ Solvation and Nanoscale Water Clustering in Choline Chloride–Urea–Water Mixtures

OS Hammond, EK Bathke, DT Bowron… - Inorganic …, 2023 - ACS Publications
Eutectic mixtures of choline chloride, urea, and water in deep eutectic solvent (DES)/water
molar hydration ratios (w) of 2, 5, and 10, with dissolved cerium salt, were measured using …

[HTML][HTML] Thermodynamic study of choline chloride-based deep eutectic solvents with dimethyl sulfoxide and isopropanol

Z Zuo, B Cao, Y Wang, C Ma, X Lu, X Ji - Journal of Molecular Liquids, 2024 - Elsevier
The thermodynamic properties of four binary mixtures of deep eutectic solvent (DES), ie,
ChCl/Gly (choline chloride+ glycerol at a molar ratio of 1: 2) and ChCl/EG (choline chloride+ …