[HTML][HTML] Macroheterocyclic compounds a key building block in new functional materials and molecular devices

OI Koifman, TA Ageeva, IP Beletskaya… - …, 2020 - cyberleninka.ru
The review discusses the latest advances in the directed synthesis and application of
macroheterocyclic compounds in science, engineering and technology, viz. as catalysts for …

NMR Spectroscopy—A Versatile Tool for Studying the Structure and Magnetic Properties of Paramagnetic Lanthanide Complexes in Solutions

YG Gorbunova, AG Martynov, KP Birin… - Russian Journal of …, 2021 - Springer
Coordination compounds of lanthanides attract increasing attention of researchers due to
their unique physical and chemical properties, including interesting optical and magnetic …

Pseudocontact shifts in lanthanide complexes with variable crystal field parameters

S Di Pietro, SL Piano, L Di Bari - Coordination Chemistry Reviews, 2011 - Elsevier
Accurate pseudocontact shifts are the basis for structural determination in solution by means
of paramagnetic NMR. Separation of pseudocontact (PCS) from Fermi contact (FC) shifts …

First example of nonlinear optical materials based on nanoconjugates of sandwich phthalocyanines with quantum dots

DO Oluwole, AV Yagodin, NC Mkhize… - … A European Journal, 2017 - Wiley Online Library
We report original, selective, and efficient approaches to novel nonlinear optical (NLO)
materials, namely homoleptic double‐and triple‐decker europium (III) complexes 2 and 3 …

NMR thermosensing properties on binuclear triple-decker complexes of terbium (III) and dysprosium (III) with 15-crown-5-phthalocyanine

SP Babailov, MA Polovkova, GA Kirakosyan… - Sensors and Actuators A …, 2021 - Elsevier
In this paper, we have firstly demonstrated the thermosensing properties of binuclear triple-
decker terbium (III) and dysprosium (III) complexes with 15-crown-5-phthalocyanine Tb 2 …

Cation-induced dimerization of heteroleptic crown-substituted trisphthalocyaninates as revealed by X-ray diffraction and NMR spectroscopy

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2020 - ACS Publications
We report comprehensive X-ray diffraction and NMR studies of potassium-induced
dimerization of heteroleptic triple-decker crown-phthalocyaninates [(15C5) 4Pc] M (Pc) M …

Combined NMR analysis of huge residual dipolar couplings and pseudocontact shifts in terbium (III)-phthalocyaninato single molecule magnets

M Damjanovic, K Katoh, M Yamashita… - Journal of the American …, 2013 - ACS Publications
Several small paramagnetic complexes combine large hyperfine NMR shifts with large
magnetic anisotropies. The latter are a prerequisite for single molecule magnet (SMM) …

Heteroleptic Crown-Substituted Tris (phthalocyaninates) as Dynamic Supramolecular Scaffolds with Switchable Rotational States and Tunable Magnetic Properties

AG Martynov, MA Polovkova, GS Berezhnoy… - Inorganic …, 2021 - ACS Publications
Herein we report single-crystal X-ray diffraction characterization and complementary
solution studies of supramolecular interaction between potassium salts and heteroleptic …

Determination of the structural parameters of heteronuclear (phthalocyaninato) bis (crownphthalocyaninato) lanthanide (III) triple-deckers in solution by simultaneous …

MA Polovkova, AG Martynov, KP Birin… - Inorganic …, 2016 - ACS Publications
Application of a general and convenient approach to the synthesis of heteronuclear crown-
substituted triple-decker phthalocyaninates afforded two series of complexes containing one …

Ligand π‐Radical Interaction with f‐Shell Unpaired Electrons in Phthalocyaninato–Lanthanoid Single‐Molecule Magnets: A Solution NMR Spectroscopic and DFT …

M Damjanović, T Morita, K Katoh… - … A European Journal, 2015 - Wiley Online Library
The phthalocyaninato double‐decker complexes [M (obPc) 2] 0 (M= YIII, TbIII, DyIII; obPc= 2,
3, 9, 10, 16, 17, 23, 24‐octabutoxyphthalocyaninato), along with their reduced ([M (obPc) …