Electro-and solar-driven fuel synthesis with first row transition metal complexes

KE Dalle, J Warnan, JJ Leung, B Reuillard… - Chemical …, 2019 - ACS Publications
The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

Nickel complexes as molecular catalysts for water splitting and CO2 reduction

JW Wang, WJ Liu, DC Zhong, TB Lu - Coordination Chemistry Reviews, 2019 - Elsevier
One of the most appealing strategies to address the problems of global warming and energy
shortage is to develop clean and sustainable energy source. To this end, considerable …

Electrocatalytic metal–organic frameworks for energy applications

CA Downes, SC Marinescu - ChemSusChem, 2017 - Wiley Online Library
With the global energy demand expected to increase drastically over the next several
decades, the development of a sustainable energy system to meet this increase is …

Redox-active ligands for chemical, electrochemical, and photochemical molecular conversions

A Nakada, T Matsumoto, HC Chang - Coordination Chemistry Reviews, 2022 - Elsevier
A central issue in the design of reactions and catalysts based on metal complexes is the
hybridization of functional ligands with metal atoms. Recent studies have demonstrated that …

Coordination-driven electrocatalysts as an evolving wave of enthusiasm for sustainable hydrogen production

S Diyali, N Diyali, B Biswas - Coordination Chemistry Reviews, 2024 - Elsevier
Hydrogen emerges as one of the cleanest and most renewable energy resources for fossil
fuel alternatives. Commercial-scale hydrogen production through water-splitting …

Metal-assisted ligand-centered electrocatalytic hydrogen evolution upon reduction of a bis (thiosemicarbazonato) Cu (II) complex

AZ Haddad, SP Cronin, MS Mashuta… - Inorganic …, 2017 - ACS Publications
In this study, we report the electrocatalytic behavior of the neutral, monomeric Cu (II)
complex of diacetyl-bis (N-4-methyl-3-thiosemicarbazonato), CuL1, for metal-assisted ligand …

Evaluation of the H2 Evolving Activity of Benzenehexathiolate Coordination Frameworks and the Effect of Film Thickness on H2 Production

CA Downes, AJ Clough, K Chen, JW Yoo… - … applied materials & …, 2018 - ACS Publications
The design of earth-abundant catalysts for the electrochemical production of H2 from water
is important for the realization of a sustainable energy future. Incorporation of molecular …

Recent advances in the mechanisms of the hydrogen evolution reaction by non-innocent sulfur-coordinating metal complexes

M Drosou, F Kamatsos, CA Mitsopoulou - Inorganic Chemistry Frontiers, 2020 - pubs.rsc.org
Efficient hydrogen generation from aqueous protons through direct conversion of solar
energy is an essential prerequisite of a future hydrogen economy and easily accessible …

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

A Mazzeo, S Santalla, C Gaviglio, F Doctorovich… - Inorganica Chimica …, 2021 - Elsevier
The rich chemistry, low cost and availability offered by first-row transition metals have
inspired many researchers to focus on the design, preparation and testing of a wide plethora …

A bioinspired nickel (bis-dithiolene) complex as a homogeneous catalyst for carbon dioxide electroreduction

T Fogeron, TK Todorova, JP Porcher… - ACS …, 2018 - ACS Publications
Inspired by the metal active sites of formate dehydrogenase and CO-dehydrogenase, a
nickel complex containing a NiS4 motif with two dithiolene ligands mimicking molybdopterin …