Recent advances in application of 27Al NMR spectroscopy to materials science

M Haouas, F Taulelle, C Martineau - Progress in nuclear magnetic …, 2016 - Elsevier
Valuable information about the local environment of the aluminum nucleus can be obtained
through 27 Al Nuclear Magnetic Resonance (NMR) parameters like the isotropic chemical …

Acid catalysts in industrial hydrocarbon chemistry

G Busca - Chemical Reviews, 2007 - ACS Publications
The hydrocarbon era1 began at the end of the 19th century, as a result of the discovery of oil
fields in the United States and together with the development of internal combustion …

Efficient photocatalytic degradation of gaseous toluene over F-doped TiO2/exfoliated bentonite

Q Wang, B Rhimi, H Wang, C Wang - Applied Surface Science, 2020 - Elsevier
To solve the aggregation problem of TiO 2 nanomaterials and improve the catalytic
efficiency, F-doped TiO 2/exfoliated bentonite (TF/EB) composite was prepared by …

Preparation and Characterization of γ-Al2O3 with Rich Brønsted Acid Sites and Its Application in the Fluid Catalytic Cracking Process

R Feng, S Liu, P Bai, K Qiao, Y Wang… - The Journal of …, 2014 - ACS Publications
The objective of this work is to investigate the surface acidity of γ-Al2O3 after modification
and its application in reducing coke formation in the fluid catalytic cracking (FCC) process. γ …

P-derived organic cations as structure-directing agents: synthesis of a high-silica zeolite (ITQ-27) with a two-dimensional 12-ring channel system

DL Dorset, GJ Kennedy, KG Strohmaier… - Journal of the …, 2006 - ACS Publications
Recently, efforts have been made to synthesize large-pore, multidimensional zeolite
frameworks as a basis for new catalysts to improve various hydrocarbon conversions. A new …

New magnesium oxide fluorides with hydroxy groups as catalysts for Michael additions

HA Prescott, ZJ Li, E Kemnitz, J Deutsch… - Journal of Materials …, 2005 - pubs.rsc.org
Amorphous materials—magnesium oxide fluoride with hydroxy groups—of high surface
area were prepared for the first time by a soft sol–gel method involving initial fluorination and …

Surface modification of fluorinated aluminas: application of solid state NMR spectroscopy to the study of acidity and surface structure

PJ Chupas, CP Grey - Journal of Catalysis, 2004 - Elsevier
Solid-state NMR methods have been used to determine the mechanism for the fluorination
reaction of CHClF2 on alumina. The initial stages of fluorination lead to the formation of …

Synergic Effect of GaO+/Brønsted Acid in Hierarchical Ga/Al-ZSM-5 Bifunctional Catalysts for 1-Hexene Aromatization

X Su, Y Fang, X Bai, W Wu - Industrial & Engineering Chemistry …, 2019 - ACS Publications
Nano-Ga/Al-ZSM-5 zeolites are synthesized by the in situ isomorphous substitution method
(I-series) and a secondary synthesis method in a Ga (NO3) 3/NH4F solution (S-series). The …

Environmental exposure to TiO2 nanomaterials incorporated in building material

N Bossa, P Chaurand, C Levard, D Borschneck… - Environmental …, 2017 - Elsevier
Nanomaterials are increasingly being used to improve the properties and functions of
common building materials. A new type of self-cleaning cement incorporating TiO 2 …

Discerning γ-alumina surface sites with nitrogen-15 dynamic nuclear polarization surface enhanced NMR spectroscopy of adsorbed pyridine

IB Moroz, K Larmier, WC Liao… - The Journal of Physical …, 2018 - ACS Publications
Low-temperature 15N dynamic nuclear polarization surface enhanced NMR spectroscopy
(DNP SENS) of adsorbed pyridine in combination with FTIR measurements and DFT …