Tropolonate salts as acyl-transfer catalysts under thermal and photochemical conditions: reaction scope and mechanistic insights
Acyl-transfer catalysis is a frequently used tool to promote the formation of carboxylic acid
derivatives, which are important synthetic precursors and target compounds in organic …
derivatives, which are important synthetic precursors and target compounds in organic …
Exploring Heterotropones and Examining Their Propensity to Undergo [4+ 2] Cycloadditions
CL Barløse, J Faghtmann, M Kaasik, R Mastroddi… - Organic …, 2024 - ACS Publications
An efficient strategy to obtain a broad array of chiral and achiral heterotropones and their
corresponding [4+ 2] cycloadducts is disclosed. This strategy enables access to unique …
corresponding [4+ 2] cycloadducts is disclosed. This strategy enables access to unique …
Lactam-fused tropolones: a new tunable, environmentally sensitive fluorophore class
DV Schiavone, J Gallardo, DM Kapkayeva… - Organic & …, 2023 - pubs.rsc.org
Fluorescent small-molecules capable of altering their profiles in response to environmental
changes are exceptionally valuable tool compounds throughout the scientific community …
changes are exceptionally valuable tool compounds throughout the scientific community …
Novel cinnamic acid analogues: synthesis of aminotroponyl acrylates by Pd (ii)-catalysed C (sp 2)–H olefination
CK Jena, NK Sharma - Chemical Communications, 2022 - pubs.rsc.org
Cinnamic acid, a benzenoid scaffold, is a building block of various natural products. This
report describes the synthesis of new non-benzenoid cinnamate analogs, 3-(6-amino-7 …
report describes the synthesis of new non-benzenoid cinnamate analogs, 3-(6-amino-7 …
Fluorescent 2′-Deoxyuridine (dU) Analogue: Tropolonyl triazolyl-dU (tt-dU) Exhibits Solvatochromism/HeLa Cell Internalization and Its Triphosphate (tt-dUTP) Is …
This era has witnessed the development and extensive application of modified nucleosides,
including fluorescent nucleosides that clinically served humankind. Most fluorescent …
including fluorescent nucleosides that clinically served humankind. Most fluorescent …
Fluorescent DNA analog: 2-aminotroponyl-pyrrolyl-2'-deoxyuridinyl DNA oligo enhance fluorescence in DNA-duplex as compared to 2-aminotroponyl-ethynyl-2' …
The nucleobase modified fluorescent DNA and RNA analogs are synthesized by the
conjugation of aromatic scaffolds through linkers, comprising mostly ethyne/ethene or fused …
conjugation of aromatic scaffolds through linkers, comprising mostly ethyne/ethene or fused …
Tropolone‐Conjugated DNA: A Fluorescent Thymidine Analogue Exhibits Solvatochromism, Enzymatic Incorporation into DNA and HeLa Cell Internalization
Tropolone is a non‐benzenoid aromatic scaffold with unique photophysical and metal‐
chelating properties. Recently, it has been conjugated with DNA, and the photophysical …
chelating properties. Recently, it has been conjugated with DNA, and the photophysical …
Studies of Oxidopyrylium Ylide Dimers and Their Utility in the Synthesis of Densely Functionalized Troponoids
DV Schiavone - 2024 - academicworks.cuny.edu
Herein, we describe our efforts to investigate mechanistic considerations of oxidopyrylium
ylides and their use in cycloadditions to form complex bicyclic structures and the …
ylides and their use in cycloadditions to form complex bicyclic structures and the …
Tropolonate Salts as Acyl Transfer Catalysts for Esterification Reactions under Thermal and Photochemical Conditions
Acyl transfer catalysis is a frequently used tool to promote the formation of carboxylic acid
derivatives, which are important synthetic precursors and target compounds in organic …
derivatives, which are important synthetic precursors and target compounds in organic …