Reversed controlled polymerization (RCP): depolymerization from well-defined polymers to monomers
Controlled polymerization methods are well-established synthetic protocols for the design
and preparation of polymeric materials with a high degree of precision over molar mass and …
and preparation of polymeric materials with a high degree of precision over molar mass and …
Linear block copolymer synthesis
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
elastomers, bridge interphases in polymer blends, and are fundamental for the development …
Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …
recommended as reversible deactivation radical polymerization) is undoubtedly a …
Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Nitroxide-mediated radical polymerization: limitations and versatility
RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …
has been widely adopted for the preparation of a panoply of new polymer architectures …
Kinetic subtleties of nitroxide mediated polymerization
D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …
lot of investigations have focused on the kinetics of this process. During the last decade …
Living character of polymer chains prepared via nitroxide-mediated controlled free-radical polymerization of methyl methacrylate in the presence of a small amount of …
J Nicolas, C Dire, L Mueller, J Belleney… - …, 2006 - ACS Publications
This article follows a previous study (Macromolecules 2005, 38, 5485) demonstrating that
the nitroxide SG1-mediated polymerization of methyl methacrylate can be achieved at 90° C …
the nitroxide SG1-mediated polymerization of methyl methacrylate can be achieved at 90° C …
Modeling and theoretical development in controlled radical polymerization
Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …
past two decades. Numerous publications may be found in the literature reporting …
First effective nitroxide-mediated polymerization of methyl methacrylate
Y Guillaneuf, D Gigmes, SRA Marque, P Astolfi… - …, 2007 - ACS Publications
Bulk methyl methacrylate (MMA) controlled radical polymerization was carried out using two
2, 2-diphenyl-3-phenylimino-2, 3-dihydroindol-1-yloxyl nitroxide (DPAIO) based …
2, 2-diphenyl-3-phenylimino-2, 3-dihydroindol-1-yloxyl nitroxide (DPAIO) based …
Tandem living insertion and controlled radical polymerization for polyolefin–polyvinyl block copolymers
Practical synthesis of polyolefin–polyvinyl block copolymers remains a challenge for
transition‐metal catalyzed polymerizations. Common approaches functionalize polyolefins …
transition‐metal catalyzed polymerizations. Common approaches functionalize polyolefins …