Reversed controlled polymerization (RCP): depolymerization from well-defined polymers to monomers

GR Jones, HS Wang, K Parkatzidis… - Journal of the …, 2023 - ACS Publications
Controlled polymerization methods are well-established synthetic protocols for the design
and preparation of polymeric materials with a high degree of precision over molar mass and …

Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Precision polymer synthesis by controlled radical polymerization: Fusing the progress from polymer chemistry and reaction engineering

YN Zhou, JJ Li, TT Wang, YY Wu, ZH Luo - Progress in Polymer Science, 2022 - Elsevier
During the first 100 years of polymer science, controlled radical polymerization (also
recommended as reversible deactivation radical polymerization) is undoubtedly a …

Nitroxide-mediated polymerization

J Nicolas, Y Guillaneuf, C Lefay, D Bertin… - Progress in Polymer …, 2013 - Elsevier
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …

Nitroxide-mediated radical polymerization: limitations and versatility

RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …

Kinetic subtleties of nitroxide mediated polymerization

D Bertin, D Gigmes, SRA Marque… - Chemical Society Reviews, 2011 - pubs.rsc.org
Due to the academic and industrial interest of Nitroxide Mediated Polymerization (NMP), a
lot of investigations have focused on the kinetics of this process. During the last decade …

Living character of polymer chains prepared via nitroxide-mediated controlled free-radical polymerization of methyl methacrylate in the presence of a small amount of …

J Nicolas, C Dire, L Mueller, J Belleney… - …, 2006 - ACS Publications
This article follows a previous study (Macromolecules 2005, 38, 5485) demonstrating that
the nitroxide SG1-mediated polymerization of methyl methacrylate can be achieved at 90° C …

Modeling and theoretical development in controlled radical polymerization

E Mastan, X Li, S Zhu - Progress in Polymer Science, 2015 - Elsevier
Controlled radical polymerization (CRP) systems have gained increasing interests for the
past two decades. Numerous publications may be found in the literature reporting …

First effective nitroxide-mediated polymerization of methyl methacrylate

Y Guillaneuf, D Gigmes, SRA Marque, P Astolfi… - …, 2007 - ACS Publications
Bulk methyl methacrylate (MMA) controlled radical polymerization was carried out using two
2, 2-diphenyl-3-phenylimino-2, 3-dihydroindol-1-yloxyl nitroxide (DPAIO) based …

Tandem living insertion and controlled radical polymerization for polyolefin–polyvinyl block copolymers

A Keyes, H Dau, K Matyjaszewski… - Angewandte Chemie, 2022 - Wiley Online Library
Practical synthesis of polyolefin–polyvinyl block copolymers remains a challenge for
transition‐metal catalyzed polymerizations. Common approaches functionalize polyolefins …