Benefiting from the impressive increase in fundamental knowledge, the last 20 years have
shown a continuous burst of new ideas and consequently a plethora of new catalytic …

The development of synthetic methods for the introduction of the fluorine atom and
fluoroalklyl groups into organic molecules has gained increased attention. Synthetic organic …

The radical-involved 1, 2-difunctionalization of alkenes has developed into a robust tool for
preparation of complex organic molecules. Despite significant advances in this area, the …

The construction of carbon–heteroatom bonds is one of the most active areas of research in
organic chemistry because the function of organic molecules is often derived from the …

Conspectus Asymmetric functionalization of alkyl radicals represents a robust yet
underdeveloped method for efficient construction and decoration of carbon skeletons in …

Direct difunctionalization of simple alkenes, the incorporation of two functional groups onto a
carbon–carbon double bond, is of particular interest to the chemical community owing to its …

The rapid generation of molecular complexity from simple starting materials is of paramount
importance in synthetic chemistry. The unique combination of high reactivity and high …

Many reactions involving allenyl ion species have been studied, but reactions involving
allenyl radicals are less well understood, perhaps because of the inconvenience associated …

Recent protocols and reactions for catalytic radical perfluoroalkylations will be described.
The production of perfluoroalkyl radicals (RF= C n F2 n+ 1, n≥ 2), which effect both addition …

High‐valent cyclopentadienyl cobalt catalysis is a versatile tool for sustainable C− H bond
functionalizations. To harness the full potential of this strategy, control of the stereoselectivity …