Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …
methods for their functionalization require them to first be converted into a more activated …
Enable biomass-derived alcohols mediated alkylation and transfer hydrogenation
X Liu, L Huang, Y Ma, G She, P Zhou, L Zhu… - Nature …, 2024 - nature.com
A single-atom catalyst with generally regarded inert Zn–N4 motifs derived from ZIF-8 is
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …
unexpectedly efficient for the activation of alcohols, enabling alcohol-mediated alkylation …
Recent Developments of Transition‐Metal‐Catalyzed Cross‐Coupling of Nitriles and Alcohols
X Cai, X Wei, M Huang - ChemistrySelect, 2024 - Wiley Online Library
Cross‐coupling of nitriles and alcohols offers an environmentally friendly and atom‐
economical method for the synthesis of various valuable compounds. These compounds …
economical method for the synthesis of various valuable compounds. These compounds …
Copper-Catalyzed α-Alkylation of Aryl Acetonitriles with Benzyl Alcohols
M Danopoulou, LP Zorba, AP Karantoni… - The Journal of …, 2024 - ACS Publications
A highly efficient, in situ formed CuCl2/TMEDA catalytic system (TMEDA= N, N, N′, N′-
tetramethylethylene-diamine) for the cross-coupling reaction of aryl acetonitriles with benzyl …
tetramethylethylene-diamine) for the cross-coupling reaction of aryl acetonitriles with benzyl …
Copper-catalyzed C (sp 3)–H alkylation of fluorene with primary and secondary alcohols using a borrowing hydrogen method
Despite the limited success of copper-catalyzed alkylations,(NNS) CuCl proved to be an
effective catalyst for the sp3 C–H alkylation of fluorene with alcohols. Various primary …
effective catalyst for the sp3 C–H alkylation of fluorene with alcohols. Various primary …
Iron-Catalyzed sp3 C–H Alkylation of Fluorene with Primary and Secondary Alcohols: A Borrowing Hydrogen Approach
The utilization of earth-abundant, cheap, and nontoxic transition metals in important catalytic
transformations is essential for sustainable development, and iron has gained significant …
transformations is essential for sustainable development, and iron has gained significant …
Ni2P Nanoparticles Supported on N, P Co-Doped Carbon as Catalyst for α-Alkylation of Arylacetonitriles with Alcohols
T Su, J Wang, C Cai - ACS Applied Nano Materials, 2024 - ACS Publications
The nickel phosphides have garnered increasing attention as an excellent catalytic site in
the fields of electrocatalysis and hydrotreating, but their application in organic synthesis …
the fields of electrocatalysis and hydrotreating, but their application in organic synthesis …
Iron-and base-catalyzed C (α)-alkylation and one-pot sequential alkylation–hydroxylation of oxindoles with secondary alcohols
The utilization of economical and environmentally benign transition metals in crucial
catalytic processes is pivotal for sustainable advancement in synthetic organic chemistry …
catalytic processes is pivotal for sustainable advancement in synthetic organic chemistry …
Nickel Complexes Bearing Quinoline Derived NNS Donor Ligands as Catalytic Activators for N‐Alkylation of Anilines with Alcohols
D Tanwar, S Mahala, D Ahluwalia… - Chemistry–An Asian …, 2024 - Wiley Online Library
Herein, we have reported a new series of NNS‐donor ligands coordinated Ni (II) complexes
and utilized them as catalytic activator to synthesize N‐alkylated amines and 1, 2 …
and utilized them as catalytic activator to synthesize N‐alkylated amines and 1, 2 …
3d-Metal Catalyzed C–C Bond Formation Through α-Alkylation of Ester, Amide, and Nitriles with Alcohol via Dehydrogenative Coupling
The borrowing hydrogenation (BH) and acceptorless dehydrogenative coupling (ADC)
methods emerged as sustainable tools for forging carbon–carbon bonds at remarkably …
methods emerged as sustainable tools for forging carbon–carbon bonds at remarkably …