Charge transport in organic semiconductors: the perspective from nonadiabatic molecular dynamics

S Giannini, J Blumberger - Accounts of Chemical Research, 2022 - ACS Publications
Conspectus Organic semiconductors (OSs) are an exciting class of materials that have
enabled disruptive technologies in this century including large-area electronics, flexible …

[HTML][HTML] Applying Marcus theory to describe the carrier transports in organic semiconductors: Limitations and beyond

Z Shuai, W Li, J Ren, Y Jiang, H Geng - The Journal of Chemical …, 2020 - pubs.aip.org
Marcus theory has been successfully applied to molecular design for organic
semiconductors with the aid of quantum chemistry calculations for the molecular parameters …

Delocalised kinetic Monte Carlo for simulating delocalisation-enhanced charge and exciton transport in disordered materials

D Balzer, TJAM Smolders, D Blyth, SN Hood… - Chemical …, 2021 - pubs.rsc.org
Charge transport is well understood in both highly ordered materials (band conduction) or
highly disordered ones (hopping conduction). In moderately disordered materials …

Flickering Polarons Extending over Ten Nanometres Mediate Charge Transport in High‐Mobility Organic Crystals

S Giannini, OG Ziogos, A Carof, M Ellis… - Advanced Theory …, 2020 - Wiley Online Library
Progress in the design of high‐mobility organic semiconductors has been hampered by an
incomplete fundamental understanding of the elusive charge carrier dynamics mediating …

From Amorphous to Polycrystalline Rubrene: Charge Transport in Organic Semiconductors Paralleled with Silicon

J Euvrard, O Gunawan, A Kahn… - Advanced Functional …, 2022 - Wiley Online Library
While progress has been made in the design of organic semiconductors (OSCs) with
improved transport properties, the understanding of the mechanisms involved is still limited …

Evolutionary chemical space exploration for functional materials: computational organic semiconductor discovery

CY Cheng, JE Campbell, GM Day - Chemical science, 2020 - pubs.rsc.org
Computational methods, including crystal structure and property prediction, have the
potential to accelerate the materials discovery process by enabling structure prediction and …

[HTML][HTML] HAB79: A new molecular dataset for benchmarking DFT and DFTB electronic couplings against high-level ab initio calculations

OG Ziogos, A Kubas, Z Futera, W Xie… - The Journal of …, 2021 - pubs.aip.org
A new molecular dataset called HAB79 is introduced to provide ab initio reference values for
electronic couplings (transfer integrals) and to benchmark density functional theory (DFT) …

Crystal symmetry and static electron correlation greatly accelerate nonradiative dynamics in lead halide perovskites

B Smith, M Shakiba, AV Akimov - The Journal of Physical …, 2021 - ACS Publications
Using a recently developed many-body nonadiabatic molecular dynamics (NA-MD)
framework for large condensed matter systems, we study the phonon-driven nonradiative …

Ultrathin porphyrin and tetra-indole covalent organic frameworks for organic electronics applications

OG Ziogos, I Blanco, J Blumberger - The Journal of Chemical Physics, 2020 - pubs.aip.org
The electronic and charge transport properties of porphyrin and tetra-indole porphyrinoid
single layer covalent organic frameworks (COFs) are investigated by means of density …

[HTML][HTML] Ultrafast estimation of electronic couplings for electron transfer between pi-conjugated organic molecules. II

OG Ziogos, J Blumberger - The Journal of Chemical Physics, 2021 - pubs.aip.org
The development of highly efficient methods for the calculation of electronic coupling matrix
elements between the electron donor and acceptor is an important goal in theoretical …