[HTML][HTML] Dynamic nuclear polarization for sensitivity enhancement in modern solid-state NMR

ASL Thankamony, JJ Wittmann, M Kaushik… - Progress in nuclear …, 2017 - Elsevier
The field of dynamic nuclear polarization has undergone tremendous developments and
diversification since its inception more than 6 decades ago. In this review we provide an in …

Hyperpolarized water as universal sensitivity booster in biomolecular NMR

C Hilty, D Kurzbach, L Frydman - Nature protocols, 2022 - nature.com
NMR spectroscopy is the only method to access the structural dynamics of biomolecules at
high (atomistic) resolution in their native solution state. However, this method's low …

High-field pulsed EPR spectroscopy under magic angle spinning

O Nir-Arad, AB Fialkov, DH Shlomi, N Manukovsky… - Science …, 2024 - science.org
In this work, we demonstrate the first pulsed electron paramagnetic resonance (EPR)
experiments performed under magic angle spinning (MAS) at high magnetic field. Unlike …

Frémy's salt as a low-persistence hyperpolarization agent: efficient dynamic nuclear polarization plus rapid radical scavenging

M Negroni, E Turhan, T Kress, M Ceillier… - Journal of the …, 2022 - ACS Publications
Nuclear magnetic resonance (NMR) spectroscopy is a key technique for molecular structure
determination in solution. However, due to its low sensitivity, many efforts have been made …

Large cross-effect dynamic nuclear polarisation enhancements with kilowatt inverting chirped pulses at 94 GHz

Y Zhao, H El Mkami, RI Hunter, G Casano… - Communications …, 2023 - nature.com
Dynamic nuclear polarisation (DNP) is a process that transfers electron spin polarisation to
nuclei by applying resonant microwave radiation, and has been widely used to improve the …

[图书][B] Handbook of high field dynamic nuclear polarization

VK Michaelis, RG Griffin, B Corzilius, S Vega - 2019 - books.google.com
Addresses Dynamic Nuclear Polarization (DNP) as a technique for sensitivity-enhancement
in solid-state NMR spectroscopy This comprehensive handbook is a compendium of the …

Crossover from a Solid Effect to Thermal Mixing 1H Dynamic Nuclear Polarization with Trityl-OX063

A Equbal, Y Li, T Tabassum, S Han - The Journal of Physical …, 2020 - ACS Publications
Trityl-OX063 is a narrow-line, water-soluble, and biocompatible polarizing agent, widely
used for dynamic nuclear polarization (DNP) amplified NMR of 13C, but not of the abundant …

Role of electron spin dynamics and coupling network in designing dynamic nuclear polarization

A Equbal, SK Jain, Y Li, K Tagami, X Wang… - Progress in Nuclear …, 2021 - Elsevier
Dynamic nuclear polarization (DNP) has emerged as a powerful sensitivity booster of
nuclear magnetic resonance (NMR) spectroscopy for the characterization of biological …

Millimeter-wave sources for DNP-NMR

M Blank, K Felch, V Michaelis, R Griffin… - Handbook of High …, 2020 - books.google.com
The past several decades have seen a renewed and growing interest in solid-state dynamic
nuclear polarization (DNP) enhanced nuclear magnetic resonance (NMR) spectroscopy for …

1H Thermal Mixing Dynamic Nuclear Polarization with BDPA as Polarizing Agents

Y Li, A Equbal, T Tabassum, S Han - The Journal of Physical …, 2020 - ACS Publications
Dynamic Nuclear Polarization (DNP) is a sensitivity enhancing technique for Nuclear
Magnetic Resonance. A recent discovery of Overhauser Effect (OE) DNP in insulating …