Recent advances in the chemistry and applications of N-heterocyclic carbenes

P Bellotti, M Koy, MN Hopkinson, F Glorius - Nature Reviews Chemistry, 2021 - nature.com
N-Heterocyclic carbenes, despite being isolated and characterized three decades ago, still
capture scientists' interest as versatile, modular and strongly coordinating moieties. In the …

N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids

A Knebel, A Bavykina, SJ Datta, L Sundermann… - Nature Materials, 2020 - nature.com
The combination of well-defined molecular cavities and chemical functionality makes
crystalline porous solids attractive for a great number of technological applications, from …

Ligand design in ligand‐protected gold nanoclusters

B Zhang, J Chen, Y Cao, OJH Chai, J Xie - Small, 2021 - Wiley Online Library
The design of surface ligands is crucial for ligand‐protected gold nanoclusters (Au NCs).
Besides providing good protection for Au NCs, the surface ligands also play the following …

N-heterocyclic carbene-functionalized magic-number gold nanoclusters

MR Narouz, KM Osten, PJ Unsworth, RWY Man… - Nature …, 2019 - nature.com
Magic-number gold nanoclusters are atomically precise nanomaterials that have enabled
unprecedented insight into structure–property relationships in nanoscience. Thiolates are …

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

H Shen, G Tian, Z Xu, L Wang, Q Wu, Y Zhang… - Coordination Chemistry …, 2022 - Elsevier
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …

Nanoparticles targeting macrophages as potential clinical therapeutic agents against cancer and inflammation

G Hu, M Guo, J Xu, F Wu, J Fan, Q Huang… - Frontiers in …, 2019 - frontiersin.org
With the development of nanotechnology, significant progress has been made in the design,
and manufacture of nanoparticles (NPs) for use in clinical treatments. Recent increases in …

Fundamentals and applications of N-heterocyclic carbene functionalized gold surfaces and nanoparticles

G Kaur, RL Thimes, JP Camden… - Chemical …, 2022 - pubs.rsc.org
The discovery of N-heterocyclic carbenes (NHCs) revolutionized organometallic chemistry
due to their strong metal–ligand bonds. These strong bonds also lend enhanced stability to …

On-surface synthesis of ballbot-type N-heterocyclic carbene polymers

J Ren, M Koy, H Osthues, BS Lammers, C Gutheil… - Nature Chemistry, 2023 - nature.com
N-Heterocyclic carbenes (NHCs) are established ligands for metal complexes and surfaces.
Here we go beyond monomeric NHCs and report on the synthesis of NHC polymers on gold …