Hypervalent iodine compounds as environmentally friendly and relatively inexpensive
reagents have properties similar to transition metals. They are employed as alternatives to …

The preparation, structure, and chemistry of hypervalent iodine compounds are reviewed
with emphasis on their synthetic application. Compounds of iodine possess reactivity similar …

As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …

The term “C–H functionalisation” incorporates C–H activation followed by its transformation.
In a single line, this can be defined as the conversion of carbon–hydrogen bonds into …

The Cδ− H amination of unactivated, secondary C− H bonds to form a broad range of
functionalized pyrrolidines has been developed by a triiodide (I3−)‐mediated strategy. By in …

C–H functionalization is a very active research field that has attracted the interest of
scientists from many disciplines. This Outlook describes the collaborative efforts within the …

Electrochemical generation of N-acyloxy amidyl radicals via an inner-sphere electron-
transfer process is described for the first time. With NaBr as the catalyst and electrolyte, the …

A conceptually new and synthetically valuable cross‐dehydrogenative benzylic C (sp3)–H
amination reaction is reported by visible‐light photoredox catalysis. This protocol employs …

Using α, α-difluoromethylene alkyne as a nontraditional one-carbon reaction partner, a
synthetically novel method for the construction of isoindolin-1-one derivatives via Rh (III) …

An organocatalytic site-selective electrochemical method for the benzylic C–H amination
reactions of alkylarenes with azoles through hydrogen evolution has been developed. The …