Heterometallic molecular architectures based on fluorinated β-diketone ligands
VI Saloutin, YO Edilova, YS Kudyakova, YV Burgart… - Molecules, 2022 - mdpi.com
This review summarizes the data on the synthesis of coordination compounds containing
two or more different metal ions based on fluorinated β-diketonates. Heterometallic systems …
two or more different metal ions based on fluorinated β-diketonates. Heterometallic systems …
Surface modulation and chromium complexation: all-in-one solution for the Cr (VI) sequestration with bifunctional molecules
X Gao, Y Zhang, F Li, B Tian, X Wang… - Environmental …, 2020 - ACS Publications
The sulfidation of zero valent iron (ZVI) to an Fe@ FeS x (S-ZVI) composite has been
intensively explored in the ZVI field. Yet, further benefits from the FeS x coating layer are …
intensively explored in the ZVI field. Yet, further benefits from the FeS x coating layer are …
Synthesis Strategies and Structures of Molecular Heterometallic Oxo Clusters
T Minato - ChemPlusChem, 2024 - Wiley Online Library
Multinuclear heterometallic oxo clusters, composed of two or more different metal cations
bridged by oxo ligands, represent an important class of molecular complexes known for their …
bridged by oxo ligands, represent an important class of molecular complexes known for their …
Heterometallic Molecular and Ionic Isomers
Numerous descriptions of structural isomerism in metal complexes do not list any molecular
vs ionic isomers. At the same time, one of the most striking examples of structural isomerism …
vs ionic isomers. At the same time, one of the most striking examples of structural isomerism …
Heterotrimetallic Precursor with 2:2:1 Metal Ratio Requiring at Least a Pentanuclear Molecular Assembly
This work represents an important step in the quest to make hetero multi metallic molecules
featuring specific metal types and complicated metal ratios. The rational design, synthesis …
featuring specific metal types and complicated metal ratios. The rational design, synthesis …
Synthesis, Structure, and Characterizations of a Volatile/Soluble Heterometallic Hexanuclear Precursor [NaMn2(thd)4(OAc)]2
The paper describes a hetero bi metallic mixed-ligand hexanuclear precursor [NaMn2 (thd)
4 (OAc)] 2 (1)(thd= 2, 2, 6, 6-tetramethyl-3, 5-heptadionate; OAc= acetate) that was designed …
4 (OAc)] 2 (1)(thd= 2, 2, 6, 6-tetramethyl-3, 5-heptadionate; OAc= acetate) that was designed …
Two polymorph modifications of tris (hexafluoroacetylacetonato) iron (III) revealed: is that common for other trivalent metals?
J Chang, JN Defeo, Z Wei… - Crystal Structure …, 2024 - journals.iucr.org
A long-standing issue about the correct identification of an important starting reagent, iron
(III) hexafluoroacetylacetonate, Fe (hfac) 3 (1), has been resolved. The tris-chelated …
(III) hexafluoroacetylacetonate, Fe (hfac) 3 (1), has been resolved. The tris-chelated …
Revealing redox isomerism in trichromium imides by anomalous diffraction
AK Bartholomew, RA Musgrave, KJ Anderton… - Chemical …, 2021 - pubs.rsc.org
In polynuclear biological active sites, multiple electrons are needed for turnover, and the
distribution of these electrons among the metal sites is affected by the structure of the active …
distribution of these electrons among the metal sites is affected by the structure of the active …