When “dark” is bright: the scarcely explored electrophilic profile of the indolyl core (dark‐
side) continues to inspire developments in organic synthesis by means of new catalytic …

Dearomatization reactions represent a versatile approach for the preparation of three‐
dimensionally (3D) privileged cyclic moieties from simple planar aromatic compounds …

We report the use of electrochemistry to perform a direct oxidative dearomatization of
indoles leading to 2, 3-dialkoxy or 2, 3-diazido indolines under undivided conditions at a …

Indole-tethered ynones form an intramolecular electron donor–acceptor complex that can
undergo visible-light-induced charge transfer to promote thiyl radical generation from thiols …

Abstract A cobalt‐promoted electrochemical 1, 2‐diarylation of alkenes with electron‐rich
aromatic hydrocarbons via direct dual C− H functionalizations is described, which employs a …

This Account summarizes our involvement in the development of dearomatization reactions
of indoles that has for origin a total synthesis problematic. We present the effort from our …

We report an efficient and environmentally friendly electrochemical approach to perform the
bromo cyclization of tryptophol, tryptamine and tryptophan derivatives. The 3a …

We have developed a straightforward FeCl3 promoted synthesis of dihydropyrrolo [2, 1‐a]
isoquinolines through formal (3+ 2) cycloaddition/oxidative aromatization cascade of …

The diastereoselective synthesis of α-amino phosphonate derivatives embedded in
spirocyclic indolines is reported. The present method proceeds via the dearomative addition …

We describe a simple and sustainable MgBr2‐mediated electrochemical dearomative
dihydroxylation and hydroxycyclization reactions of indoles with water. MgBr2 is used in …