Two-dimensional polymers and polymerizations

AM Evans, MJ Strauss, AR Corcos, Z Hirani… - Chemical …, 2021 - ACS Publications
Synthetic chemists have developed robust methods to synthesize discrete molecules, linear
and branched polymers, and disordered cross-linked networks. However, two-dimensional …

Engineering covalent organic frameworks as heterogeneous photocatalysts for organic transformations

H Chen, HS Jena, X Feng, K Leus… - Angewandte Chemie …, 2022 - Wiley Online Library
Covalent organic frameworks (COFs) are an emerging category of organic polymers with
highly porous crystalline structures. In the last decade, reports on the use of COFs as …

Optoelectronic processes in covalent organic frameworks

N Keller, T Bein - Chemical Society Reviews, 2021 - pubs.rsc.org
Covalent organic frameworks (COFs) are crystalline porous materials constructed from
molecular building blocks using diverse linkage chemistries. Their modular construction …

Covalent organic frameworks: design, synthesis, and functions

K Geng, T He, R Liu, S Dalapati, KT Tan, Z Li… - Chemical …, 2020 - ACS Publications
Covalent organic frameworks (COFs) are a class of crystalline porous organic polymers with
permanent porosity and highly ordered structures. Unlike other polymers, a significant …

2D covalent organic frameworks: from synthetic strategies to advanced optical‐electrical‐magnetic functionalities

C Wang, Z Zhang, Y Zhu, C Yang, J Wu… - Advanced …, 2022 - Wiley Online Library
Covalent organic frameworks (COFs), an emerging class of organic crystalline polymers with
highly oriented structures and permanent porosity, can adopt 2D or 3D architectures …

Advances in conjugated microporous polymers

JSM Lee, AI Cooper - Chemical reviews, 2020 - ACS Publications
Conjugated microporous polymers (CMPs) are a unique class of materials that combine
extended π-conjugation with a permanently microporous skeleton. Since their discovery in …

Realizing Photocatalytic Overall Water Splitting by Modulating the Thickness‐Induced Reaction Energy Barrier of Fluorenone‐Based Covalent Organic Frameworks

R Shen, C Qin, L Hao, X Li, P Zhang, X Li - Advanced Materials, 2023 - Wiley Online Library
Direct photocatalytic hydrogen and oxygen evolution from water splitting is an attractive
approach for producing chemical fuels. In this work, a novel fluorenone‐based covalent …

Recent progress on phase engineering of nanomaterials

Q Yun, Y Ge, Z Shi, J Liu, X Wang, A Zhang… - Chemical …, 2023 - ACS Publications
As a key structural parameter, phase depicts the arrangement of atoms in materials.
Normally, a nanomaterial exists in its thermodynamically stable crystal phase. With the …

Perfluoroalkyl-functionalized covalent organic frameworks with superhydrophobicity for anhydrous proton conduction

X Wu, Y Hong, B Xu, Y Nishiyama… - Journal of the …, 2020 - ACS Publications
The development of anhydrous proton-conducting materials is critical for the fabrication of
high-temperature (> 100° C) polymer electrolyte membrane fuel cells (HT-PEMFCs) and …

Tuning crystallinity and stacking of two-dimensional covalent organic frameworks through side-chain interactions

CE Pelkowski, A Natraj, CD Malliakas… - Journal of the …, 2023 - ACS Publications
Two-dimensional covalent organic frameworks (2D COFs) form as layered 2D polymers
whose sheets stack through high-surface-area, noncovalent interactions that can give rise to …