Hydrosilylation reactions of functionalized alkenes
Y Naganawa, K Inomata, K Sato, Y Nakajima - Tetrahedron Letters, 2020 - Elsevier
Hydrosilylation of alkenes is an important reaction for the production of organosilicon
compounds such as industrially important silicones and silane coupling agents. To …
compounds such as industrially important silicones and silane coupling agents. To …
Recent developments in alkene hydrosilylation utilizing manganese catalysts
N Katayama, Y Obora - Tetrahedron Letters, 2023 - Elsevier
Hydrosilylation of alkenes is an important process in the synthesis of organosilicon
compounds in which an Si–H species is added across a carbon–carbon double bond (C …
compounds in which an Si–H species is added across a carbon–carbon double bond (C …
Nickel-catalyzed regiodivergent hydrosilylation of α-(fluoroalkyl) styrenes without defluorination
D Bai, K Zhong, L Chang, Y Qiao, F Wu, G Xu… - Nature …, 2024 - nature.com
The fluoroalkyl-containing organic molecules are widely used in drug discovery and material
science. Herein, we report ligand regulated nickel (0)-catalyzed regiodivergent …
science. Herein, we report ligand regulated nickel (0)-catalyzed regiodivergent …
(NHC) Ni (0)-catalyzed branched-selective alkene hydrosilylation with secondary and tertiary silanes
AS Chang, KE Kawamura, HS Henness… - ACS …, 2022 - ACS Publications
Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …
precursors to silicone materials that are widely incorporated in our everyday lives. The …
Cobalt (I)-catalyzed transformation of Si–H bonds: H/D exchange in hydrosilanes and hydrosilylation of olefins
L Denker, D Wullschläger, JP Martínez… - ACS …, 2023 - ACS Publications
The amino imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N═ C (N i PrCMe) 2] is
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …
Asymmetric cobalt‐catalyzed regioselective hydrosilylation/cyclization of 1, 6‐Enynes
Y You, S Ge - Angewandte Chemie, 2021 - Wiley Online Library
We report an enantioselective cobalt‐catalyzed hydrosilylation/cyclization reaction of 1, 6‐
enynes with secondary and tertiary hydrosilanes employing a catalyst generated in situ from …
enynes with secondary and tertiary hydrosilanes employing a catalyst generated in situ from …
Nickel-Catalyzed Hydrofluorination in Unactivated Alkenes: Regio-and Enantioselective C–F Bond Formation
Catalytic formation of a regio-and enantioselective C–F bond chiral center from readily
available alkenes is a crucial goal, yet it continues to pose significant challenges in organic …
available alkenes is a crucial goal, yet it continues to pose significant challenges in organic …
Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis
CS Kuai, DW Ji, CY Zhao, H Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
A method for the regiodivergent and stereoselective hydrosilylation of the basic industrial
feedstock isoprene with unactivated silanes has been developed using earth‐abundant iron …
feedstock isoprene with unactivated silanes has been developed using earth‐abundant iron …
Aqueous amine-tolerant [2+ 2] photocycloadditions of unactivated olefins
CMF Mansson, NZ Burns - Journal of the American Chemical …, 2022 - ACS Publications
The Kochi–Salomon reaction is the only photochemical [2+ 2] cycloaddition capable of
combining two electronically unactivated olefins into a cyclobutane. Yet, the reaction has …
combining two electronically unactivated olefins into a cyclobutane. Yet, the reaction has …
Transition-metal-and solvent-free regioselective hydrosilylation of alkenes and allenes enabled by catalytic sodium tert-butoxide
β-Selective hydrosilylation products of alkenes are of industrial importance, and the
development of methods with Markovnikov selectivity is a growing area of research and still …
development of methods with Markovnikov selectivity is a growing area of research and still …