Hydrosilylation reactions of functionalized alkenes

Y Naganawa, K Inomata, K Sato, Y Nakajima - Tetrahedron Letters, 2020 - Elsevier
Hydrosilylation of alkenes is an important reaction for the production of organosilicon
compounds such as industrially important silicones and silane coupling agents. To …

Recent developments in alkene hydrosilylation utilizing manganese catalysts

N Katayama, Y Obora - Tetrahedron Letters, 2023 - Elsevier
Hydrosilylation of alkenes is an important process in the synthesis of organosilicon
compounds in which an Si–H species is added across a carbon–carbon double bond (C …

Nickel-catalyzed regiodivergent hydrosilylation of α-(fluoroalkyl) styrenes without defluorination

D Bai, K Zhong, L Chang, Y Qiao, F Wu, G Xu… - Nature …, 2024 - nature.com
The fluoroalkyl-containing organic molecules are widely used in drug discovery and material
science. Herein, we report ligand regulated nickel (0)-catalyzed regiodivergent …

(NHC) Ni (0)-catalyzed branched-selective alkene hydrosilylation with secondary and tertiary silanes

AS Chang, KE Kawamura, HS Henness… - ACS …, 2022 - ACS Publications
Hydrosilylation is a valuable approach for the construction of organosilanes, which are
precursors to silicone materials that are widely incorporated in our everyday lives. The …

Cobalt (I)-catalyzed transformation of Si–H bonds: H/D exchange in hydrosilanes and hydrosilylation of olefins

L Denker, D Wullschläger, JP Martínez… - ACS …, 2023 - ACS Publications
The amino imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N═ C (N i PrCMe) 2] is
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …

Asymmetric cobalt‐catalyzed regioselective hydrosilylation/cyclization of 1, 6‐Enynes

Y You, S Ge - Angewandte Chemie, 2021 - Wiley Online Library
We report an enantioselective cobalt‐catalyzed hydrosilylation/cyclization reaction of 1, 6‐
enynes with secondary and tertiary hydrosilanes employing a catalyst generated in situ from …

Nickel-Catalyzed Hydrofluorination in Unactivated Alkenes: Regio-and Enantioselective C–F Bond Formation

C Lee, M Kim, S Han, D Kim… - Journal of the American …, 2024 - ACS Publications
Catalytic formation of a regio-and enantioselective C–F bond chiral center from readily
available alkenes is a crucial goal, yet it continues to pose significant challenges in organic …

Ligand‐Regulated Regiodivergent Hydrosilylation of Isoprene under Iron Catalysis

CS Kuai, DW Ji, CY Zhao, H Liu… - Angewandte Chemie …, 2020 - Wiley Online Library
A method for the regiodivergent and stereoselective hydrosilylation of the basic industrial
feedstock isoprene with unactivated silanes has been developed using earth‐abundant iron …

Aqueous amine-tolerant [2+ 2] photocycloadditions of unactivated olefins

CMF Mansson, NZ Burns - Journal of the American Chemical …, 2022 - ACS Publications
The Kochi–Salomon reaction is the only photochemical [2+ 2] cycloaddition capable of
combining two electronically unactivated olefins into a cyclobutane. Yet, the reaction has …

Transition-metal-and solvent-free regioselective hydrosilylation of alkenes and allenes enabled by catalytic sodium tert-butoxide

S Saini, DK Gupta, R Bhawar, S Siddiqui, MV Mane… - Green …, 2023 - pubs.rsc.org
β-Selective hydrosilylation products of alkenes are of industrial importance, and the
development of methods with Markovnikov selectivity is a growing area of research and still …