Renaissance of pyridine-oxazolines as chiral ligands for asymmetric catalysis
G Yang, W Zhang - Chemical Society Reviews, 2018 - pubs.rsc.org
Oxazoline-containing ligands have been widely employed in numerous asymmetric catalytic
reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier …
reactions. Pyridine-oxazoline-type ligands, a class of hybrid ligands, were designed earlier …
Enantioselective desymmetrization reactions in asymmetric catalysis
C Nájera, F Foubelo, JM Sansano, M Yus - Tetrahedron, 2022 - Elsevier
This review covers the recent developments (since 2015) of enantioselective
desymmetrization reactions using metal-catalyzed, organocatalyzed and enzymatic …
desymmetrization reactions using metal-catalyzed, organocatalyzed and enzymatic …
Recent Advances of Catalytic Enantioselective Heck Reactions and Reductive‐Heck Reactions
JQ Xie, RX Liang, YX Jia - Chinese Journal of Chemistry, 2021 - Wiley Online Library
Heck reaction is one of the most important carbon‐carbon bond forming reactions with wide
applications in organic synthesis. Considerable advances of enantioselective Heck reaction …
applications in organic synthesis. Considerable advances of enantioselective Heck reaction …
Palladium-Catalyzed Synthesis of Linked Bis-Heterocycles─ Synthesis and Investigation of Photophysical Properties
A palladium-catalyzed domino C–N coupling/Cacchi reaction is reported. Design of
photoluminescent bis-heterocycles, aided by density functional theory calculations, was …
photoluminescent bis-heterocycles, aided by density functional theory calculations, was …
Alcohols as Substrates in Transition-Metal-Catalyzed Arylation, Alkylation, and Related Reactions
Alcohols are abundant and attractive feedstock molecules for organic synthesis. Many
methods for their functionalization require them to first be converted into a more activated …
methods for their functionalization require them to first be converted into a more activated …
A combined experimental and computational study of 3-bromo-5-(2, 5-difluorophenyl) pyridine and 3, 5-bis (naphthalen-1-yl) pyridine: Insight into the synthesis …
Carbon-carbon coupling play a vital role in the synthetic field of organic chemistry. Two
novel pyridine derivatives: 3-bromo-5-(2, 5-difluorophenyl) pyridine (1) and 3, 5-bis …
novel pyridine derivatives: 3-bromo-5-(2, 5-difluorophenyl) pyridine (1) and 3, 5-bis …
Harnessing noncovalent interactions in dual-catalytic enantioselective Heck–Matsuda arylation
The use of more than one catalyst in one-pot reaction conditions has become a rapidly
evolving protocol in the development of asymmetric catalysis. The lack of molecular insights …
evolving protocol in the development of asymmetric catalysis. The lack of molecular insights …
Enantioselective Heck–Matsuda arylations through chiral anion phase‐transfer of aryl diazonium salts
A mild, asymmetric Heck–Matsuda reaction of five‐, six‐and seven‐membered ring alkenes
and aryl diazonium salts is presented. High yields and enantioselectivities were achieved …
and aryl diazonium salts is presented. High yields and enantioselectivities were achieved …
Immobilization of Trifluoromethyl-Substituted Pyridine-Oxazoline Ligand and Its Application in Asymmetric Continuous Flow Synthesis of Benzosultams
M Kocúrik, J Bartáček, P Drabina… - The Journal of …, 2023 - ACS Publications
This study presents an improved synthetic route to ligand (S)-4-(tert-butyl)-2-(5-
(trifluoromethyl) pyridin-2-yl)-4, 5-dihydrooxazole and its application as a highly active and …
(trifluoromethyl) pyridin-2-yl)-4, 5-dihydrooxazole and its application as a highly active and …
N-heterocyclic carbene based nickel and palladium complexes: A DFT comparison of the Mizoroki–Heck catalytic cycles
A theoretical investigation has been performed on nickel–and palladium–N-heterocyclic
carbene (NHC) complexes in the Mizoroki–Heck (MH) reaction. A density functional theory …
carbene (NHC) complexes in the Mizoroki–Heck (MH) reaction. A density functional theory …