C–H activation
T Rogge, N Kaplaneris, N Chatani, J Kim… - Nature Reviews …, 2021 - nature.com
Transition metal-catalysed C–H activation has emerged as an increasingly powerful platform
for molecular syntheses, enabling applications to natural product syntheses, late-stage …
for molecular syntheses, enabling applications to natural product syntheses, late-stage …
New strategies for the transition-metal catalyzed synthesis of aliphatic amines
A Trowbridge, SM Walton, MJ Gaunt - Chemical reviews, 2020 - ACS Publications
Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …
simple, readily available feedstocks have become a cornerstone of modern synthetic …
3d transition metals for C–H activation
C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …
notable applications to material sciences, crop protection, drug discovery, and …
Shortwave infrared polymethine fluorophores matched to excitation lasers enable non-invasive, multicolour in vivo imaging in real time
ED Cosco, AL Spearman, S Ramakrishnan… - Nature …, 2020 - nature.com
High-resolution, multiplexed experiments are a staple in cellular imaging. Analogous
experiments in animals are challenging, however, due to substantial scattering and …
experiments in animals are challenging, however, due to substantial scattering and …
Transition-metal-catalyzed C–H alkylation using alkenes
Alkylation reactions represent an important organic transformation to form C–C bonds. In
addition to conventional approaches with alkyl halides or sulfonates as alkylating agents …
addition to conventional approaches with alkyl halides or sulfonates as alkylating agents …
Titanium catalysis for the synthesis of fine chemicals–development and trends
M Manßen, LL Schafer - Chemical Society Reviews, 2020 - pubs.rsc.org
Titanium is the second most abundant transition metal and is already a key player in
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
important industrial processes (eg polyethylene). Titanium is an attractive metal to use for …
CO2-Promoted Reactions: An Emerging Concept for the Synthesis of Fine Chemicals and Pharmaceuticals
Carbon dioxide is a nontoxic and abundant chemical and has been widely used as a C1
building block for the synthesis of highly important chemicals. This greenhouse gas also has …
building block for the synthesis of highly important chemicals. This greenhouse gas also has …
Functionalization of Organic Molecules by Transition‐Metal‐Catalyzed C(sp3)H Activation
R Jazzar, J Hitce, A Renaudat… - … A European Journal, 2010 - Wiley Online Library
Transition‐metal‐catalyzed C H activation has recently emerged as a powerful tool for the
functionalization of organic molecules. While many efforts have focused on the …
functionalization of organic molecules. While many efforts have focused on the …
Transition metal-catalysed carbene-and nitrene transfer to carbon monoxide and isocyanides
Transition metal-catalysed carbene-and nitrene transfer to the C1-building blocks carbon
monoxide and isocyanides provides heteroallenes (ie ketenes, isocyanates, ketenimines …
monoxide and isocyanides provides heteroallenes (ie ketenes, isocyanates, ketenimines …
Direct α-alkylation of primary aliphatic amines enabled by CO2 and electrostatics
Primary aliphatic amines are important building blocks in organic synthesis due to the
presence of a synthetically versatile NH2 group. N-functionalization of primary amines is …
presence of a synthetically versatile NH2 group. N-functionalization of primary amines is …